Detail of "14696-82-3"

CAS Number:
14696-82-3
Name:
Iodine azide (I(N3))(7CI,8CI,9CI)
Molecular Structure:
Formula:
IN3
Molecular Weight:
168.93
Synonyms:
Iodineazide; Iodine(I) azide; Iodoazide; Nitrogen iodide (N3I)
Safety:
A very shock- and friction-sensitive explosive. Incompatible with sulfur-containing alkenes. When heated to decomposition it emits very toxic fumes of I⁻ and NO_x. See also IODINE. Details

Please post your buying leads,so that our qualified suppliers will soon contact you!
*Required Fields

Reaction of benzofuran with iodine azide: formation of cis- and trans-2,3-diazido-2,3-dihydrobenzofurans: Reaction of benzofuran with iodine azide: formation of cis- and trans-2,3-diazido-2,3-dihydrobenzofurans. Kwon, Sundo; Okada, Tomoko; Ikeda, Masazumi; Tamura, Yasumitsu (Fac. Pharm. Sci., Osaka Univ., Suita, Japan). Heterocycles, 6(1), 33-6 (English) 1977. CODEN: HTCYAM. DOCUMENT TYPE: Journal CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) The title reaction gave 93% of a mixt. of I and II in a molar ratio (NMR); I and II were sepd. 62095-86-7 and 14696-82-3 are also in the experiment. by preparative thin layer chromatog. Treatment of either I or II with KOH gave 3-azidobenzofuran. Refluxing I and II with MeO2CC.tplbond.CCO2Me gave the corresponding 1:2 cycloadducts in 50 and 18% yield, resp. .

The crystal structure of 5-methyl-1-(octahydro-1-iodo-1H-1-inden-4-yl)-1H-tetrazole: The crystal structure of 5-methyl-1-(octahydro-1-iodo-1H-1-inden-4-yl)-1H-tetrazole. Puttaraja; Gowda, D. S. Sake; Duax, William L. (Cent.In this study， 89824-34-0 and 14696-82-3 are also used. Coll., Bangalore Univ., Bangalore, India). J. Crystallogr. Spectrosc. Res., 14(1), 13-20 (English) 1984. CODEN: JCREDB. ISSN: 0277-8068. DOCUMENT TYPE: Journal CA Section: 75 (Crystallography and Liquid Crystals) Section cross-reference(s): 28 The title compd. is monoclinic, space group P21/a, with a 11.586(2), b 10.617(1), c 10.417(1) ?, and b 94.567(2)°; dc = 1.71 and dm = 1.70 for Z = 4. The structure was solved by Patterson and Fourier methods and refined to an R = 0.031 for 1620 reflections. The connectivity and conformation of the addn. product of cis-1,5-cyclononadiene and iodine azide was, thus, detd. The compd. contains a chair-conformation cyclohexane ring that is cis-fused to a cyclopentane ring. The cyclopentane ring has an envelope conformation and an equatorially oriented I. A planar tetrazole ring is axially substituted on the cyclohexane ring. The plane of the tetrazole ring makes a dihedral angle of 69.6° with the av. plane of the carbon atoms of the cyclohexane ring. At. coordinates are given. .