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14858-73-2

Basic Information
CAS No.: 14858-73-2
Name: bis(2-ethylhexyl) carbonate
Article Data: 11
Molecular Structure:
Molecular Structure of 14858-73-2 (bis(2-ethylhexyl) carbonate)
Formula: C17H34 O3
Molecular Weight: 286.455
Synonyms: Bis(2-ethylhexyl)carbonate; Cetiol Sun; Di(2-ethylhexyl) carbonate; Dialcarb H 1; Tegosoft DEC
Density: 0.895g/cm3
Melting Point: <-50 °C
Boiling Point: 342.6°Cat760mmHg
Flash Point: 131.3°C
Solubility: 30μg/L at 20℃
PSA: 35.53000
LogP: 5.57240
Synthetic route
104-76-7

2-Ethylhexyl alcohol

14858-73-2

bis(2-ethylhexyl) carbonate

Conditions
ConditionsYield
With diisobutylaluminum hydride; triphenylphosphine In toluene at 160 - 270℃; for 16h;87%
104-76-7

2-Ethylhexyl alcohol

105-58-8

Diethyl carbonate

14858-73-2

bis(2-ethylhexyl) carbonate

Conditions
ConditionsYield
With di(n-butyl)tin oxide at 140℃; for 26h;70.6%
104-76-7

2-Ethylhexyl alcohol

124-38-9

carbon dioxide

14858-73-2

bis(2-ethylhexyl) carbonate

Conditions
ConditionsYield
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran for 18h;61%
1,1,3,3-tetrabutyl-1,3-bis(2-ethylhexyloxy)distannoxane In water at 120℃; for 600h; Industry scale; Autoclave;
67-56-1

methanol

124-38-9

carbon dioxide

14858-73-2

bis(2-ethylhexyl) carbonate

Conditions
ConditionsYield
dibutyl-bis(2-ethylhexyloxy)tin; 1,1,3,3-tetrabutyl-1,3-bis(2-ethylhexyloxy)distannoxane In 2-Ethylhexyl alcohol at 120℃; under 22502.3 - 26252.6 Torr; for 4h;25%
149746-25-8

dibutyl-bis(2-ethylhexyloxy)tin

10301-02-7

1,1,3,3-tetrabutyl-1,3-bis(2-ethylhexyloxy)distannoxane

3644-24-4

tributyl-(2-ethylhexyloxy)-tin

124-38-9

carbon dioxide

14858-73-2

bis(2-ethylhexyl) carbonate

Conditions
ConditionsYield
at 120℃; under 30003 Torr; for 3.16667h; Product distribution / selectivity;25%
149746-25-8

dibutyl-bis(2-ethylhexyloxy)tin

10301-02-7

1,1,3,3-tetrabutyl-1,3-bis(2-ethylhexyloxy)distannoxane

3644-24-4

tributyl-(2-ethylhexyloxy)-tin

124-38-9

carbon dioxide

A

carbon dioxide adduct of tributyltin(2-ethylhexyloxide)

B

14858-73-2

bis(2-ethylhexyl) carbonate

Conditions
ConditionsYield
at 120℃; under 30003 Torr; for 3.16667h; Product distribution / selectivity;A 0.1%
B 25%
104-76-7

2-Ethylhexyl alcohol

142-72-3, 92123-19-8

magnesium acetate

14858-73-2

bis(2-ethylhexyl) carbonate

Conditions
ConditionsYield
With triphenylphosphine; urea
149746-25-8

dibutyl-bis(2-ethylhexyloxy)tin

3644-24-4

tributyl-(2-ethylhexyloxy)-tin

124-38-9

carbon dioxide

14858-73-2

bis(2-ethylhexyl) carbonate

Conditions
ConditionsYield
at 130℃; Gas phase;
149746-25-8

dibutyl-bis(2-ethylhexyloxy)tin

124-38-9

carbon dioxide

14858-73-2

bis(2-ethylhexyl) carbonate

Conditions
ConditionsYield
1,1,3,3-tetrabutyl-1,3-bis(2-ethylhexyloxy)distannoxane at 120℃; under 30003 Torr; for 4h; Autoclave; Industry scale;
149746-25-8

dibutyl-bis(2-ethylhexyloxy)tin

10301-02-7

1,1,3,3-tetrabutyl-1,3-bis(2-ethylhexyloxy)distannoxane

124-38-9

carbon dioxide

14858-73-2

bis(2-ethylhexyl) carbonate

Conditions
ConditionsYield
at 100 - 120℃; under 30753.1 Torr; for 4h; Large scale;
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