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14874-82-9

Basic Information
CAS No.: 14874-82-9
Name: Dicarbonylacetylacetonato rhodium(I)
Molecular Structure:
Molecular Structure of 14874-82-9 (Dicarbonylacetylacetonato rhodium(I))
Formula: C7H7O4Rh
Molecular Weight: 258.03
Synonyms: Rhodium,(2,4-pentanedionato)dicarbonyl- (7CI);Rhodium, dicarbonyl(2,4-pentanedionato)-(8CI);Rhodium, dicarbonyl(2,4-pentanedionato-O,O')-, (SP-4-2)-;Rhodium,dicarbonyl(2,4-pentanedionato-kO,kO')-, (SP-4-2)- (9CI);(Acetylacetonate)dicarbonylrhodium;(Acetylacetonato)dicarbonyl rhodium;Acetylacetonatobis(carbonyl)rhodium;Acetylacetonatodicarbonylrhodium(I);Acetylacetonatorhodium dicarbonyl;Dicarbonyl(2,4-pentanedionato)rhodium;Dicarbonyl(2,4-pentanedionato-kO,kO')rhodium;Dicarbonylacetylacetonatorhodium;Dicarbonylacetylacetonatorhodium(I);Dicarbonylrhodium acetylacetonate;Dicarbonylrhodium(I) acetylacetonate;Rhodium acetylacetonate dicarbonyl;Rhodium biscarbonyl acetylacetonate;Rhodium dicarbonylacetylacetonate;
EINECS: 238-947-9
Density: 1.96[at 20℃]
Melting Point: 154-156 °C(lit.)
Solubility: Insoluble in water
Appearance: Red/green crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-37/39
PSA: 26.30000
LogP: 0.54410
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    Items Standard Result Assay 98%min ----------------------------------------------------------------------------------------------

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Chemistry

Product Name: Dicarbonylacetylacetonato rhodium(I)
Molecular Structure of Dicarbonylacetylacetonato rhodium(I) (CAS NO.14523-22-9):

Molecular Formula: C7H7O4Rh
Molecular Weight: 258.0336
CAS NO: 14523-22-9
Melting point: 154-156 °C 
H bond acceptors: 4
Freely Rotating Bonds: 3
Polar Surface Area: 26.3 Å2
SMILES: [C-]#[O+].CC(=O)\C=C(\C)O[Rh].[O+]#[C-] 
InChI: InChI=1/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;/rC5H7O2Rh.2CO/c1-4(6)3-5(2)7-8;2*1-2/h3H,1-2H3;;/b5-3-;; 
InChIKey: BZCAWKOPWNIDOC-DVFPFCNYBD
Std. InChI: InChI=1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;; 
Std. InChIKey: BZCAWKOPWNIDOC-FGSKAQBVSA-M
Synonyms of Dicarbonylacetylacetonato rhodium(I) (CAS NO.14523-22-9): EINECS 238-540-6 ; NSC 120116 ; Di-mu-chloro-bis(dicarbonylrhodium)

Safety Profile

Hazard Codes of Dicarbonylacetylacetonato rhodium(I) (CAS NO.14523-22-9): IrritantXi,FlammableF,ToxicT
Risk Statements: 36/37/38 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-37/39 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S37/39: Wear suitable gloves and eye/face protection.
RIDADR: 3282
WGK Germany: 3
TSCA: No
HazardClass: 6.1
PackingGroup: III