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14883-34-2

Basic Information
CAS No.: 14883-34-2
Name: Tripotassium trioxalatoferrate
Molecular Structure:
Molecular Structure of 14883-34-2 (Tripotassium trioxalatoferrate)
Formula: C6FeO12K3
Molecular Weight: 437.201
Synonyms: Ferrate(3-),tris(oxalato)-, tripotassium (8CI);Ferrate(3-), tris[ethanedioato(2-)-O,O']-,tripotassium, (OC-6-11)-;Ferrate(3-), tris[ethanedioato(2-)-kO1,kO2]-, tripotassium, (OC-6-11)- (9CI);Potassiumoxalatoferrate(III) (K3[Fe(C2O4)3]) (6CI);Potassium trioxalatoferrate(III)(7CI);Iron potassium oxalate, K3Fe(C2O4)3;NSC 2915;NSC 43607;Oxalic acid,iron(3+) potassium salt (3:1:3);Potassium ferrioxalate;Potassium ironoxalate, K3Fe(C2O4)3;Potassium iron(3+) oxalate;Potassiumtris(oxalato)ferrate(III);
EINECS: 238-954-7
Density: 2.13 g/cm3
Melting Point: 230 °C
Boiling Point: 365.1°C at 760 mmHg
Flash Point: 188.8°C
PSA: 188.21000
LogP: -7.22300
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Chemistry

Molecule structure of Tripotassium trioxalatoferrate (CAS NO.14883-34-2):

Molecular Weight: 437.20 g/mol
Molecular Formula: C6FeO12K3
Appearance emerald green hydrated crystals 
Density: 2.13 g/cm3
Melting Point: 230 °C
EINECS: 238-954-7

Uses

 Tripotassium trioxalatoferrate (CAS NO.14883-34-2) is often used in chemical actinometry.

Production

The Tripotassium trioxalatoferrate can be made from the reaction between potassium oxalate, iron(III) sulfate and barium oxalate :
Fe2(SO4)3 + 3 Ba(C2O4) + 3 K2(C2O4) → 2 K3[Fe(C2O4)3] + 3 BaSO4
The reactants are dissolved in water and heated for about 1.5 hours. BaSO4 precipitates out leaving behind the newly formed complex in solution. The complex can then be got by filtering off the BaSO4 and cooling the solution so that it crystallizes out.

Safety Profile

RIDADR: 3288
HazardClass: 6.1(b)
PackingGroup: III

Specification

 Tripotassium trioxalatoferrate (CAS NO.14883-34-2) is also named as Kalium-Eisen(III)-oxalat-3-hydrat ; PotassiumIron(III)oxalatetrihydrate . In solution, the Tripotassium trioxalatoferrate dissociates to give the ferrioxalate anion, [Fe(C2O4)3]3-, which appears fluorescent green in color.