Detail of "14949-69-0"

CAS Number:
14949-69-0
Name:
Nickel,bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-kO2,kO4)-, (SP-4-1)-
Molecular Structure:
Formula:
C10H2 F12 Ni O4
Molecular Weight:
526.84
Synonyms:
2,4-Pentanedione,1,1,1,5,5,5-hexafluoro-, nickel deriv. (6CI); Nickel, bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)-(7CI,8CI); Nickel, bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-O,O')-,(SP-4-1)-; Nickel, bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-kO,kO')-, (SP-4-1)- (9CI);Bis(1,1,1,5,5,5,-hexafluoropentane-2,4-dionato)nickel(II);Bis(1,1,1,5,5,5-hexafluoro-2,4-pentandiono)nickel (II);Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-O,O')nickel(II);Bis(hexafluoroacetylacetonato)nickel; Nickel bis(hexafluoroacetylacetonate);Nickel(II) hexafluoroacetylacetonate
Density:
g/cm³
Melting Point:
211-213°C
Boiling Point:
114.1°Cat760mmHg
Flash Point:
22.8°C
Safety:
Risk Statements 20/21/22-43
Safety Statements 36/37/39-45
TSCA No
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Linear oligomerization of propylene with nickel complex catalysts: Linear oligomerization of propylene with nickel complex catalysts. Zhou, Keyan; Gao, Zhanxian; Keim, Wilhelm (Inst. Appl. Org. Chem., Dalian Inst. Technol., Dalian, Peop. Rep. China). Int. Congr. Catal., [Proc.], 8th, Volume 5, V429-V439. Verlag Chemie: Weinheim, Fed. Rep. Ger. (English) 1984. CODEN: 55DBAG. DOCUMENT TYPE: Conference CA Section: 22 (Physical Organic Chemistry) Section cross-reference(s): 36 The oligomerization and dimerization of propylene [115-07-1] in the presence of nickel bis(1,1,1,5,5,5-hexafluoro-2,4-pentadione) [14949-69-0]-(iso-Bu)3Al [100-99-2] or unsupported and supported bis(h-1,5-cyclooctadiene)nickel-hexafluoroacetylacetone catalysts were studied with emphasis on the dimerization mechanism. The effects of temp. and Al/Ni ratio on the activity of Ni-(iso-Bu)3Al catalyst system were detd.Except for chemicals metioned above, 71900-00-0 and 691-37-2 are also used. A dimerization mechanism is discussed. .

Oligomerization reaction of 1-butene: Oligomerization reaction of 1-butene. I. Catalytic behavior of 1,1,1,5,5,5-hexafluoro-2,4-pentanedionatonickel/diethylaluminum ethoxide. Gao, Zhanxian; Zhang, Aili; Yu, Jing; Zhou, Keyan (Dalian Inst. Technol., Dalian, Peop. Rep. China). Yingyong Huaxue, 4(1), 40-3 (Chinese) 1987. CODEN: YIHUED. DOCUMENT TYPE: Journal CA Section: 35 (Chemistry of Synthetic High Polymers) Section cross-reference(s): 45 The 1,1,1,5,5,5-hexafluoroacetylacetonatonickel [14949-69-0]-Et2AlOEt [1586-92-1] system was an efficient catalyst for linear oligomerization of 1-butene [106-98-9]. The catalytic activity was dependent on temp. 1586-92-1 and 14949-69-0 which are cas registry numbers of substances are two of reagents here. and catalyst compn. This system also catalyzed isomerization and hydrogenation of 1-butene. .