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150-39-0

Basic Information
CAS No.: 150-39-0
Name: N-(2-Hydroxyethyl)ethylenediaminetriacetic acid
Article Data: 7
Molecular Structure:
Molecular Structure of 150-39-0 (N-(2-Hydroxyethyl)ethylenediaminetriacetic acid)
Formula: C10H18N2O7
Molecular Weight: 278.262
Synonyms: Glycine,N-(carboxymethyl)-N'-(2-hydroxyethyl)-N,N'-ethylenedi- (8CI);(2-Hydroxyethyl)ethylenediaminetriacetic acid;Chel DM Acid;(Hydroxyethyl)ethylenediaminetriacetic acid;Hamp-OL;Hydroxyethylethylenediaminotriacetic acid;N-(2-Hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid;N-(Hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid;N-(Hydroxyethyl)ethylenediaminetriacetic acid;NSC 7341;N'-(2-Hydroxyethyl)ethylenediamine-N,N,N'-triacetic acid;Oxyethylethylenediaminetriacetic acid;HEDTA;HEEDTA;Detarol;DissolvineH;
EINECS: 205-759-3
Density: 1.468 g/cm3
Melting Point: 212 °C (dec.)(lit.)
Boiling Point: 572.5 °C at 760 mmHg
Flash Point: 300 °C
Solubility: soluble
Appearance: White crystalline powder
Hazard Symbols: HarmfulXn, IrritantXi
Risk Codes: 36/37/38-22-40-20/21/22
Safety: 26-37/39-36-22
PSA: 138.61000
LogP: -2.16350
Synthetic route
50-00-0

formaldehyd

143-33-9

sodium cyanide

111-41-1

2-(2-Aminoethylamino)ethanol

150-39-0

N-(2-hydroxyethyl)ethylenediaminetriacetic acid

Conditions
ConditionsYield
With sodium hydroxide

Fe(3+)*3ClO4(1-)*7H2O=[Fe(ClO4)3]*7H2O

150-39-0

N-(2-hydroxyethyl)ethylenediaminetriacetic acid

[Fe(III)(N-hydroxyethyl-ethylenediamine triacetate)(H2O)]

Conditions
ConditionsYield
In water a ligand (0.01 mol) was suspended in water; the Fe-contg. compd. (0.01 mol) was added with stirring; acetone was added; the crystals were pptd. overnighnt being placed in a refrigerator; elem. anal.;89%
150-39-0

N-(2-hydroxyethyl)ethylenediaminetriacetic acid

7718-98-1

vanadium(III) chloride

497-19-8

sodium carbonate

{N'-(2-hydroxyethyl)ethylenediamine-N,N,N'-triacetato}aquavanadium(III)*2H2O

Conditions
ConditionsYield
In water under N2; ligand in H2O neutralized with Na2CO3; anhydrous VCl3 added, soln. stirred for a few minutes; crystals collected, washed with cold water and acetone; elem. anal.;85%

malachite

150-39-0

N-(2-hydroxyethyl)ethylenediaminetriacetic acid

205673-75-2

[(N-(2-hydroxyethyl)-N'-carboxymethyl-1,2-ethylenediamine-N,N'-diacetato)copper(II) hydrate]

Conditions
ConditionsYield
In water byproducts: CO2, CuO; N-(2-hydroxyethyl)-1,2-ethylenediamine-N,N,N'-triacetic acid and Cu2CO3(OH)2 in water heated in a Kitasato-flask (t<50 °C), stirred at reduced pressure to remove CO2, then heated at 60 °C, stirred 30 min, cooled to room temp.; filtered, slow evapn. of solvent in 3-4 wk, crystn., filtered, washed with cold water, air-dried, recrystn. from hot water; elem. anal.;85%

samarium(III) carbonate

150-39-0

N-(2-hydroxyethyl)ethylenediaminetriacetic acid

Sm(3+)*C10H15N2O7(3-)*5H2O=Sm(C10H15N2O7)*5H2O

Conditions
ConditionsYield
With water In water in hot soln.; addn. of isopropanol with vigorous shaking then addn. of alcohol, washing (isopropanol), drying in air (24 h);80%

yttrium(III) carbonate

150-39-0

N-(2-hydroxyethyl)ethylenediaminetriacetic acid

Y(3+)*C10H15N2O7(3-)*6H2O=Y(C10H15N2O7)*6H2O

Conditions
ConditionsYield
With water In water in hot soln.; addn. of isopropanol with vigorous shaking then addn. of alcohol, washing (isopropanol), drying in air (24 h);80%

neodymium carbonate

150-39-0

N-(2-hydroxyethyl)ethylenediaminetriacetic acid

Nd(3+)*C10H15N2O7(3-)*6H2O=Nd(C10H15N2O7)*6H2O

Conditions
ConditionsYield
With water In water in hot soln.; addn. of isopropanol with vigorous shaking then addn. of alcohol, washing (isopropanol), drying in air (24 h);80%

gadolinium(III) carbonate

150-39-0

N-(2-hydroxyethyl)ethylenediaminetriacetic acid

Gd(3+)*C10H15N2O7(3-)*6H2O=Gd(C10H15N2O7)*6H2O

Conditions
ConditionsYield
With water In water in hot soln.; addn. of isopropanol with vigorous shaking then addn. of alcohol, washing (isopropanol), drying in air (24 h);80%

europium(III) carbonate

150-39-0

N-(2-hydroxyethyl)ethylenediaminetriacetic acid

Eu(3+)*C10H15N2O7(3-)*5H2O=Eu(C10H15N2O7)*5H2O

Conditions
ConditionsYield
With water In water in hot soln.; addn. of isopropanol with vigorous shaking then addn. of alcohol, washing (isopropanol), drying in air (24 h);80%

thorium(IV) nitrate pentahydrate

150-39-0

N-(2-hydroxyethyl)ethylenediaminetriacetic acid

1310-73-2

sodium hydroxide

Th6(N-(2-hydroxoethyl)ethylenediaminetriacetate)

Conditions
ConditionsYield
In water for 48h; pH=8.4;72.1%
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    N-(2-Hydroxyethyl)ethylenediaminetriacetic acid

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    Product Name: N-(2-Hydroxyethyl)ethylenediaminetriacetic acid CAS: 150-39-0 MF: C10H18N2O7 MW: 278.26 EINECS: 205-759-3 Mol File: 150-39-0.mol N-(2-Hydroxyethyl)ethylenediaminetriacetic acid Structure N-(2-Hydroxyethyl)ethylenedia

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Chemistry

Molecular Formula: C10H18N2O7
Molecular Weight:
278.260 g/mol 
EINECS: 205-759-3
Water Solubility: Soluble
Flash Point: 300 °C
Density: 1.468 g/cm3
Index of Refraction: 1.568 
Melting Point: 212-214 °C 
Enthalpy of Vaporization: 98.57 kJ/mol  
Vapour Pressure: 1.72E-15 mmHg at 25 °C
Boiling Point: 572.5 °C at 760 mmHg
The molecular structure of N-(2-Hydroxyethyl)ethylenediaminetriacetic acid (CAS NO.150-39-0): 
                                        
IUPAC: 2-[2-[Bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid
Product Category of N-(2-Hydroxyethyl)ethylenediaminetriacetic acid (CAS NO.150-39-0): Analytical Chemistry;Chelating Reagents;Complexones;EDTA Analogs

Uses

 N-(2-Hydroxyethyl)ethylenediaminetriacetic acid (CAS NO.150-39-0) can be used not as a binder, but also for the textile, pharmaceutical industries and rare element of the refining.

Toxicity Data With Reference

1.    

ipr-rat LD50:337 mg/kg

    AHRTAN    Arhiv za Higijenu Rada i Toksikologiju. Archives of Industrial Hygiene and Toxicology. 13 (1962),295.
2.    

ipr-mus LD50:259 mg/kg

    ARTODN    Archives of Toxicology. 57 (1985),212.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes such as NOx.
Hazard Symbols:Xn:
Risk Codes: R22;R36/37/38 
R22: Harmful if swallowed
R36/37/38 : Irritating to eyes, respiratory system and skin
Safety Description: S26;S37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice
S37/39 : Wear suitable gloves and eye/face protection

Specification

  N-(2-Hydroxyethyl)ethylenediaminetriacetic acid , its cas register number is 150-39-0. It also can be called N-Carboxymethyl-N'-(2-hydroxyethyl)-N,N'-ethylenediglycine ; N-(2-Hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid and HEDTA .