Detail of "1515-95-3"

Reference

Gaseous ionic acetylation of some substitute anisoles

Gaseous ionic acetylation of some substitute anisoles. Evidence for an intermediate .pi. complex. Chatfield, Dale A.; Bursey, Maurice M. (Venable and Kenan Chem. Lab., Univ. North Carolina, Chapel Hill, N. C., USA). J. Am. Chem. Soc., 98(21), 6492-5 (English) 1976. CODEN: JACSAT. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Rates of reaction of MeCO+, MeCO(COMe)Me+, and MeCOCO(COMe)Me+ with methyl-substituted anisoles are linearly related for different reagent ions. The results require a .pi.In this experiment, several chemicals are used like 1515-95-3 and 100-66-3 complex with transfer to O. Halogenated anisoles react with these ions too slowly to measure, giving in some cases products of reactions of ions derived from the arom. compd. .

Catalytic transfer reduction of carbonyl compounds

Brieger, Gottfried; Fu, Tzuu-Heng (Dep. Chem., Oakland Univ., Rochester, Mich., USA). J. Chem. Soc., Chem. Commun., (19), 757 (English) 1976. 7446-70-0 and 1515-95-3 are also in the experiment. CODEN: JCCCAT. DOCUMENT TYPE: Journal CA Section: 25 (Noncondensed Aromatic Compounds) Arom. aldehydes and ketones were reduced to the corresponding hydrocarbons by catalytic transfer redn. using cyclohexene or (+)-limonene as donor, Pd-C as catalyst, and a Lewis acid promotor such as FeCl3. Thus 4-MeOC6H4COMe with (+)-limonene in the presence of 10% Pd-C, with FeCl3 as promoter, gave 90% 4-MeOC6H4Et. .