Detail of "15274-43-8"

Reference

New trends in the synthesis of organosilicon monomers by hydrosilylation of unsaturated compounds

New trends in the synthesis of organosilicon monomers by hydrosilylation of unsaturated compounds. Reikhsfel'd, V. O. (USSR). Kremniiorg. Soedin. Mater. Ikh Osn., Tr. Soveshch. Khim. Prakt. Primen. Kremniiorg. Soedin., 5th, Meeting Date 1981, 5-13. Edited by: Reikhsfel'd, V. O. Nauka, Leningr. Otd.: Leningrad, USSR. (Russian) 1984. CODEN: 52OZAK. DOCUMENT TYPE: Conference CA Section: 35 (Chemistry of Synthetic High Polymers) A mechanism for the action of Ni complex catalysts in the title reaction is proposed, based on IR and magnetic susceptibility studies of structural changes in (Bu3P)3NiCl2 [15274-43-8] during hydrosilylation of 1-octene [111-66-0] by MeSiHCl2 [75-54-7]. The activity of silica gel-supported Pt complex catalysts in the reaction of styrene [100-42-5] with MeSiHCl2 was demonstrated.

Photochemistry and photocatalytic reactions of mixed-ligand azido transition metal complexes

Photochemistry and photocatalytic reactions of mixed-ligand azido transition metal complexes. Hennig, H.; Stich, R.; Knoll, H.; Rehorek, D.; Stufkens, D. J. (Sekt. Chem., Univ.Some commonly used reagents like 15274-43-8 and 29894-57-3 are used in this experiment. Leipzig, Leipzig O-7010, Germany). Coord. Chem. Rev., 111, 131-44 (English) 1991. CODEN: CCHRAM. ISSN: 0010-8545. DOCUMENT TYPE: Journal CA Section: 74 (Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes) Section cross-reference(s): 29, 67 Photolysis is studied of mixed-ligand azido complexes of Pd(II), Pt(II), and Ni(II) with both phosphine and diphosphine ligands and aliph. and arom. diimine ligands resp. Formation of intermediate isomerization products, metal(I) complexes and azidyl radicals is discused. Coordinatively unsatd. metal(0) complexes which are formed as the ultimate products in the course of photolysis exhibit catalytic activity. Thus, oxidative addn. was obsd. with photochem. generated Pt(0) and Pd(0) species, whereas photoinduced cyclotrimerization of alkynes was detected in the presence mixed-ligand azido Ni(II) complexes. .