Detail of "15321-51-4"

Reference

Schiff-base complexes of tetracarbonyliron from enneacarbonyldi-iron

Schiff-base complexes of tetracarbonyliron from enneacarbonyldi-iron.Some chemicals with cas registry numbers like 15321-51-4 and 61459-55-0 are also used. Cardaci, Giuseppe; Bellachioma, Gianfranco (Inst. Phys. Chem., Univ. Perugia, Perugia, Italy). J. Chem. Soc., Dalton Trans., (17), 1735-7 (English) 1976. CODEN: JCDTBI. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) The reaction between Fe2(CO)9 and Schiff bases PhCH:CHCH:NC6H4R (I; R = H, 4-Cl, 4-Br, 3-Br, 4-F, 4-I, 4-Me, 4-OMe) and R1R2R3R4C6HCH:NC6H4OMe-4 (II; R1, R2, R3, R4 = H, Me, or OMe) was reexamd., and the product complexes isolated and characterized by elemental anal. and spectra. The first stage of the reaction gives Fe(CO)4L (L = I, II) in which the Fe is bonded to the N lone-pair electrons of the Schiff base. With I the second stage of the reaction gives Fe(.eta.-PhCH:CHCH:NC6H4R)(CO)3. Ligands II with unsubstituted benzene ring ortho positions give Fe2(CO)6L. .

Kinetics of thermal decomposition of iron nonacarbonyl

Kinetics of thermal decomposition of iron nonacarbonyl. Baev, A.Several substances are used for example 15321-51-4 which is its cas registry number. K.; Gaidym, I. L.; Dem'yanchuk, V. V. (USSR). Zh. Fiz. Khim., 50(10), 2713 (Russian) 1976. CODEN: ZFKHA9. DOCUMENT TYPE: Journal CA Section: 67 (Catalysis and Reaction Kinetics) The method of gas displacement was used to study the kinetics for the thermal decompn. of Fe nonacarbonyl. The rate consts. and activation energies were detd. .