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15607-89-3

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CAS No.: 15607-89-3
Name: SULFUR BROMOPENTAFLUORIDE PLEASE INQUIRE
Article Data: 3
Molecular Structure:
Molecular Structure of 15607-89-3 (SULFUR BROMOPENTAFLUORIDE PLEASE INQUIRE)
Formula: BrF5 S
Molecular Weight: 206.962
Synonyms: Sulfurbromide fluoride (SBrF5) (7CI,8CI); Bromopentafluorosulfur; Pentafluorosulfurbromide; Sulfur bromide pentafluoride
Density: 2.098 g/cm3(Temp: 20.1 °C)
Melting Point: -79°C
Boiling Point: 3.1°C
PSA: 25.30000
LogP: 3.59480
Synthetic route
5714-22-7

disulfur decafluoride

7726-95-6

bromine

15607-89-3

pentafluorosulfanyl bromide

Conditions
ConditionsYield
byproducts: SF6, SF4; 150°C, 16 h, procedure described by T. A. Kovacina, A. D. Berry,and W. B. Fox, J. Fluorine Chem., 7,430, (1976); trap-to-trap fractionation (-63°C, -116°C, -196°C), addn. of Hg to the trap at 0°C;85%
In neat (no solvent) reaction; distn.;
112043-76-2

SF5N(Br)CF3

15607-89-3

pentafluorosulfanyl bromide

Conditions
ConditionsYield
With CO In neat (no solvent) byproducts: CF3N=C=O, Br2; excess CO, room temp., 4 d; fractional distn., mixt. of SF5Br/CF3N=C=O not separated;
15607-89-3

pentafluorosulfanyl bromide

79410-50-7

Perfluoro-n-butanesulfonyl hypochlorite

79410-59-6

pentafluoro(nonafluorobutanesulfonato)sulfur(VI)

Conditions
ConditionsYield
-111 to 0°C;80%
-111 to 0°C;80%
15607-89-3

pentafluorosulfanyl bromide

10102-44-0

Nitrogen dioxide

508233-73-6

pentafluoronitrosulfane

Conditions
ConditionsYield
With CsF In neat (no solvent) byproducts: Br2, SOF4, SF4; Irradiation (UV/VIS); mixt. irradiated for 12 h; condensed at -196°C; warmed to -78°C; volatiles transferred into cylinder cooled to -196°C cntg.CsF; distilled through -78, -130, -196°C traps; recovered from -130°C trap;3%
15607-89-3

pentafluorosulfanyl bromide

612-17-9

1,4-dihydronaphthalene

880871-79-4

3-bromo-2-pentafluorosulfanyl-1,2,3,4-tetrahydro-naphthalene

Conditions
ConditionsYield
With potassium fluoride; triethyl borane In hexanes; pentane at -50℃; for 2h;
15607-89-3

pentafluorosulfanyl bromide

hydrogen

A

10546-01-7

sulfurpentafluoride

B

10035-10-6, 12258-64-9

hydrogen bromide

Conditions
ConditionsYield
In gaseous matrix Kinetics; reaction of H (produced on microwave discharge) and SF5Br in Ar; not isolated;
15607-89-3

pentafluorosulfanyl bromide

40779-99-5

Lithium; 2,3,4,5,6-pentafluoro-benzenethiolate

A

1494-06-0

bis(pentafluorophenyl) disulfide

B

52082-75-4

bis(pentafluorophenyl)trisulfane

15607-89-3

pentafluorosulfanyl bromide

xenon

Conditions
ConditionsYield
In gaseous matrix Kinetics; byproducts: SF5; Xe/Ar mixt. flowing through inner tube and SF5Br/Ar mixt. through outertube of flowing afterglow reactor (coaxial mixing type), combined gas flows passing through rolled tantalum electrodes (ca. 0.7 cm diam., sepd.by ca. 1 cm, 200-250 V);
15607-89-3

pentafluorosulfanyl bromide

1076-44-4

pentafluorophenyl lithium

26346-84-9

bis(pentafluorophenyl) sulfoxide

Conditions
ConditionsYield
In diethyl ether -78°C, 5 h;50-60
15607-89-3

pentafluorosulfanyl bromide

13997-93-8

bromine(I) fluorosulfate

81439-35-2

pentafluorosulfur fluorosulfonate

Conditions
ConditionsYield
In not given BrSO3F was reacted with SF5Br according to Johri, K. K.; Katsuhara, Y.; DesMarteau, D. D.; J. Fluorine Chem. 1982, 19, 227;
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