Detail of "15635-87-7"

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Experiment and modeling of mass-transfer processes of volatile metal beta-diketonates

Experiment and modeling of mass-transfer processes of volatile metal beta-diketonates. II. Study of mass-transfer process of tris-(acetylacetonato) iridium(III). Gelfond, Nikolai V.; Mikheev, Alexander N.Chemical with cas number 15635-87-7 also plays role.; Morozova, Natalia B.; Gelfond, Natalia E.; Igumenov, Igor K. (Institute of Inorganic Chemistry, Novosibirsk 630090, Russia). International Journal of Thermal Sciences, 42(8), 725-730 (English) 2003 Editions Scientifiques et Medicales Elsevier. CODEN: IJTSFZ. ISSN: 1290-0729. DOCUMENT TYPE: Journal CA Section: 65 (General Physical Chemistry) Mass transfer process in tris-(acetylacetonato) iridium(III), Ir(acac)3, is investigated using a special installation with non-stop weighing at atm. pressure. Mass transfer rates for this compd. are measured under various exptl. conditions (within temp. range 186-242 °C, at carrier gas flow rate from 1 to 40 l×h-1) for powder and single crystal samples. The effect of purifn. and storage method on mass transfer rate is stated for this compd. Math. models describing sublimation processes are proposed. Comparison with earlier obtained results for tris-(acetylacetonato) chromium(III), Cr(acac)3, is carried out. .