Detail of > 16029-98-4
- CAS Number:
- 16029-98-4
- Name:
Iodotrimethylsilane
- Formula:
- C3H9ISi
- Molecular Structure:

- Synonyms:
- trimethyliodosilane;iodo-trimethyl-silane;Silane, iodotrimethyl-;Trimethyl Iodo Silane;(Iodo)-trimethylsilane;Trimethylsilyl iodide;Trimethyliodosilane(TMIS);trimethyliodo silane;
- Molecular Weight:
- 200.09
- EINECS:
- 240-171-0
- Density:
- 1.508 g/cm3
- Melting Point:
- <0°C
- Boiling Point:
- 101.5 °C at 760 mmHg
- Flash Point:
- 15.2 °C
- Solubility:
- reacts with water
- Appearance:
- Straw liquid
- Hazard Symbols:
F,
C- Risk Codes:
- 11-14-34
- Safety:
- 16-26-36/37/39-43-45-25Details
- Transport Information:
- UN 2924 3/PG 2
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- 16029-98-4Iodotrimethylsilane
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Reference
- Monomeric N-hydroxyethylated amides
- Monomeric N-hydroxyethylated amides. Sonnet, Philip E.; Piotrowski, Edwin G.; Wise, William B.; Micich, Thomas J. (Anim. Biomater. Res. Unit, USDA, Philadelphia, PA 19118, USA). JAOCS, J. Am. Oil Chem. Soc.Several substances like 38914-83-9 may be metioned in this study., 63(12), 1579-83 (English) 1986. CODEN: JJASDH. DOCUMENT TYPE: Journal CA Section: 46 (Surface Active Agents and Detergents) Oxyethylated amides that are good wetting agents were prepd. as mixts. by allowing amides to react with ethylene oxide under base catalysis. Individual components of such mixts. could be synthesized by allowing 1-octylaziridines [38914-83-9] to react with p-toluenesulfonic acid in mono-Me ethers of di, tri and tetraethylene glycol used as solvents. The amino ethers were then acylated, and the Me ether group was removed with Me3SiI [16029-98-4] from the resulting amide ethers. .
- Synthetic methods and reactions
- Synthetic methods and reactions. Part 120. Iodotrimethylsilane-catalyzed preparation of methoxymethyl ethers of primary and secondary alcohols with dimethoxymethane. 16029-98-4 and 79137-09-0 are also occured in this study. Olah, George A.; Husain, Altaf; Narang, Subhash C. (Hydrocarb. Res. Inst., Univ. South. California, Los Angeles, CA 90089, USA). Synthesis, (11), 896-7 (English) 1983. CODEN: SYNTBF. ISSN: 0039-7881. DOCUMENT TYPE: Journal CA Section: 23 (Aliphatic Compounds) The reaction of ROH (R = cyclohexylmethyl, n-heptyl, n-nonyl, n-undecyl, Me(CH2)6CHMe, Bu2CH, cholesteryl) with CH(OMe)2 in the presence of Me3SiI gave 76-95% ROCH2OMe. .
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