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1608-26-0

Basic Information
CAS No.: 1608-26-0
Name: Hexamethylphosphorous triamide
Article Data: 43
Molecular Structure:
Molecular Structure of 1608-26-0 (Hexamethylphosphorous triamide)
Formula: C6H18N3P
Molecular Weight: 163.203
Synonyms: Phosphoroustriamide, hexamethyl- (6CI,8CI,9CI);Hexametapil;Hexamethyltriamidophosphite;Hexamethyltriaminophosphine;NSC 102707;Tris(dimethylamino)phosphine;Trisdimethylaminophosphorus;
EINECS: 216-534-4
Density: 0.898 g/mL at 25 °C(lit.)
Melting Point: -44 °C
Boiling Point: 160.3 °C at 760 mmHg
Flash Point: 50.8 °C
Solubility: Reacts with water
Appearance: colourless liquid
Hazard Symbols: ToxicT, HarmfulXn, IrritantXi, FlammableF
Risk Codes: 45-46-10-40-36/37/38
Safety: 53-45-36/37/39-26-16-37/39-36
Transport Information: UN 1993 3/PG 3
PSA: 23.31000
LogP: 0.89810
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Chemistry

Chemical Name: Hexamethylphosphorous triamide
IUPAC NAME: N-[bis(Dimethylamino)phosphanyl]-N-methylmethanamine
CAS No.: 1608-26-0
EINECS: 216-534-4
RTECS: TH3390000
RTECS Class: Mutagen
EC Class: Flammable
Molecular Formula: C6H18N3P
Molecular Weight: 163.2 g/mol
Melting Point: -44 °C
Flash Point: 50.8 °C
Boiling Point: 160.3 °C at 760 mmHg
Sensitive: Moisture Sensitive
Following is the structure of Hexamethylphosphorus triamide (1608-26-0):


The chemical synonymous of Hexamethylphosphorus triamide (1608-26-0) are Hexametapil ; Hexamethyl-phosphoroustriamid ; Hexamethyltriamidophosphite ; Phosphine, tris(dimethylamino)- ; Phosphoroustriamide,hexamethyl- ; Hexamethyltriaminophosphine ; Hexamethyl phosphorus triamide

Uses

 Hexamethylphosphorus triamide (1608-26-0) is mainly used as intermediate for organic synthesis.

Toxicity Data With Reference

1.    

sln-oin-dmg-orl 1 mmol/L

    MUREAV    Mutation Research. 212 (1989),193.
2.    

sln-oin-dmg-par 3 mmol/L

    MUREAV    Mutation Research. 212 (1989),193.
3.    

otr-ham:kdy 2500 µg/L

    BJCAAI    British Journal of Cancer. 38 (1978),418.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Mutation data reported. When heated to decomposition it emits toxic vapors of NOx and POx.
Hazard Codes:
Xn: Harmful
Xi: Irritant
F: Flammable
N: Dangerous for the environment
Risk Statements about Hexamethylphosphorus triamide (1608-26-0):
R10 Flammable. 
R36/37/38 Irritating to eyes, respiratory system and skin. 
R40 Limited evidence of a carcinogenic effect. 
Safety Statements about Hexamethylphosphorus triamide (1608-26-0):
S16 Keep away from sources of ignition - No smoking. 
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 
Attention:
1. Storage: Keep away from heat, sparks, and flame. Keep container closed when not in use. Flammables-area. Storage under a nitrogen blanket has been recommended.
2. Handling: Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.