CAS No.16096-31-4,1,6-Hexanediol diglycidyl ether Suppliers

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Basic Information

Molecular Structure:
CAS No.:	16096-31-4
Name:	1,6-Hexanediol diglycidyl ether
Article Data:	7

Formula:	C₁₂H₂₂O₄
Molecular Weight:	230.304
Synonyms:	Hexane,1,6-bis(2,3-epoxypropoxy)- (6CI,8CI);1,6-Bis(glycidyloxy)hexane;1,6-Hexamethylenediol diglycidyl ether;Hexamethylene diglycidyl ether;Hexamethylene glycol diglycidyl ether;Hexanediol diglycidyl ether;NPEK 051;ZH 16;
EINECS:	240-260-4
Density:	1.076 g/cm³
Boiling Point:	328.7 °C at 760 mmHg
Flash Point:	120 °C
Appearance:	Clear liquid
PSA:	43.52000
LogP:	1.37760

Synthetic route

: 629-11-8
1,6-hexanediol

: 106-89-8
epichlorohydrin

: 16096-31-4
1,6 hexanediol diglycidyl ether

Conditions

Conditions	Yield
With tetrabutyl-ammonium chloride; sodium hydroxide In water at 40℃; for 2h;	68.2%
With tetrabutylammomium bromide; sodium hydroxide In water at 40℃; for 2h;
Etherification;
tin(IV) chloride Etherification;

: 81866-56-0
1,6-bis(allyloxy)hexane

A: 16096-31-4
1,6 hexanediol diglycidyl ether

B: 1246463-46-6
C12H22O3

Conditions

Conditions	Yield
With dihydrogen peroxide; benzonitrile; triethylamine In water at 60℃; for 25h; Conversion of starting material;	A 29% B 44%

: 629-11-8
1,6-hexanediol

: 106-89-8
epichlorohydrin

A: 16096-31-4
1,6 hexanediol diglycidyl ether

B: 6-hydroxy hexyl glycidyl ether

Conditions

Conditions	Yield
With potassium hydroxide In tetrahydrofuran for 5h; Heating;	A 14 g B 50 g

...Expand

: 629-11-8
1,6-hexanediol

: 3132-64-7
1,2-Epoxy-3-bromopropane

A: 16096-31-4
1,6 hexanediol diglycidyl ether

B: 6-hydroxy hexyl glycidyl ether

Conditions

Conditions	Yield
With potassium hydroxide In tetrahydrofuran for 7h; Heating;	A 35 g B 35 g

...Expand

: 20387-39-7
1-chloro-3-[6-(3-chloro-2-hydroxy-propoxy)-hexyloxy]-propan-2-ol

: 16096-31-4
1,6 hexanediol diglycidyl ether

Conditions

Conditions	Yield
With sodium hydride In hexane; toluene at 20℃; for 0.0833333h; Cyclization;	228 mg

: 629-11-8
1,6-hexanediol

: 16096-31-4
1,6 hexanediol diglycidyl ether

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: SnCl4 / toluene; heptane / 3 h / 90 °C 2: 228 mg / NaH / toluene; hexane / 0.08 h / 20 °C View Scheme

: 16096-31-4
1,6 hexanediol diglycidyl ether

: 871835-30-2
2-oxo-1,3-dioxolane-4-carboxylic acid

: C20H30O14

Conditions

Conditions	Yield
With chromium(III) acetylacetonate; triethylamine In tetrahydrofuran at 80℃; for 16h;	100%

: 16096-31-4
1,6 hexanediol diglycidyl ether

: (2-dimethylamino-1-(4-morpholinophenyl)-2-(4-carboxyphenylmethyl)butan-1-one)

: C60H82N4O12

Conditions

Conditions	Yield
With tetrabutylammomium bromide In acetonitrile for 10h; Reflux;	88%

: 16096-31-4
1,6 hexanediol diglycidyl ether

: 3-{[6-(2,3-dihydroxypropoxy)hexyl]oxy}-1,2-propanediol

Conditions

Conditions	Yield
With water; trifluoroacetic acid Hydrolysis; ring cleavage;	63%

: 16096-31-4
1,6 hexanediol diglycidyl ether

: 111-86-4
n-Octylamine

: 189192-11-8
di[(2-hydroxy-3-octylamino)propyloxy]hexamethylene

Conditions

Conditions	Yield
In ethanol for 4h;	105 g

Raw Materials

81866-56-0

629-11-8

20387-39-7

106-89-8

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Chemistry

Molecular Structure of Oxirane, 2,2'-(1,6-hexanediylbis(oxymethylene))bis- (CAS NO.16096-31-4):

Molecular Formula: C₁₂H₂₂O₄
Molecular Weight: 230.3007
IUPAC Name: 2-[6-(Oxiran-2-ylmethoxy)hexoxymethyl]oxirane
Synonyms of Oxirane, 2,2'-(1,6-hexanediylbis(oxymethylene))bis- (CAS NO.16096-31-4): 1,6-Hexanediol diglycidyl ether ; EINECS 240-260-4 ; 1,6-Bis(2,3-epoxypropoxy)hexane
CAS NO: 16096-31-4
Classification Code: TSCA Flag E [Subject to the Section 5(e) Consent Order of TSCA] ; TSCA Flag P [A commenced PMN (Premanufacture Notice) substance] ; TSCA Flag S [Substance is identified in a proposed or final SNUR (Significant New Use Rule) under TSCA]
Index of Refraction: 1.475
Molar Refractivity: 60.28 cm³
Molar Volume: 213.9 cm³
Surface Tension: 41.8 dyne/cm
Density: 1.076 g/cm³
Flash Point: 120 °C
Enthalpy of Vaporization: 54.85 kJ/mol
Boiling Point: 328.7 °C at 760 mmHg
Vapour Pressure of Oxirane, 2,2'-(1,6-hexanediylbis(oxymethylene))bis- (CAS NO.16096-31-4): 0.000355 mmHg at 25°C