Detail of "16115-80-3"

CAS Number:
16115-80-3
Name:
Propanedioic acid,2-amino-, 1,3-dimethyl ester, hydrochloride (1:1)
Superlist Name:
Dimethyl aminomalonate hydrochloride
Molecular Structure:
Formula:
C₅H₁₀ClNO₄
Molecular Weight:
183.5902
Synonyms:
Malonicacid, amino-, dimethyl ester, hydrochloride (6CI,8CI);Propanedioic acid, amino-,dimethyl ester, hydrochloride (9CI);Aminomalonic acid dimethyl esterhydrochloride;Dimethyl aminomalonate hydrochloride;
EINECS:
240-284-5
Density:
1.205g/cm³
Melting Point:
160 °C (dec.)(lit.)
Boiling Point:
155.7 °C at 760 mmHg
Flash Point:
33.2 °C
Appearance:
light yellow crystals or crystalline powder
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety:
26-36 Details

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2-Aminomalonic acid dimethyl ester hydrochloride

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Metabolic products of microorganisms: Metabolic products of microorganisms. Part 159. The aromatic amino acid constituents of echinocandin B: 3,4-dihydroxyhomotyrosine. Keller-Schierlein, Walter; Widmer, Joerg (Org.-Chem. Lab.Some commonly used reagents like 16115-80-3 and 61172-70-1 are used in this experiment., ETH, Zurich, Switz.). Helv. Chim. Acta, 59(6), 2021-31 (German) 1976. CODEN: HCACAV. DOCUMENT TYPE: Journal CA Section: 34 (Synthesis of Amino Acids, Peptides, and Proteins) Section cross-reference(s): 10 4-HOC6H4CH(OH)CH(OH)CH(NH2)CO2H (I) is a constituent of the antifungal antibiotic echinocandin B. When tetrahydro-echinocandin B (II) was treated with CF3CO2H and MeOH, H-Thr-Hyp-NHCH(CH2COC6H4OH-4)CO2Me was obtained. Periodate degrdn. of II gave 4-HOC6H4CHO, and I was obtained from mild acid treatment of II. 4-AcOC6H4CH2COCH2NHAc, which has been obtained from the acid hydrolysis of echinocandin B, was prepd. .