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Detail of "16321-99-6"

  • CAS Number:
  • 16321-99-6
  • Name:
  • 9H-Purin-2-amine,6-chloro-9-(2,3,5-tri-O-acetyl-b-D-ribofuranosyl)-

  • Molecular Structure:
  • Formula:
  • C16H18 Cl N5 O7
  • Molecular Weight:
  • 427.79642
  • Synonyms:
  • 9H-Purine,2-amino-6-chloro-9-b-D-ribofuranosyl-, 2',3',5'-triacetate (8CI); 9H-Purine,2-amino-6-chloro-9-b-O-ribofuranosyl-, 2',3',5'-triacetate (7CI);2-Amino-6-chloro-9-(2',3',5'-tri-O-acetyl-b-D-ribofuranosyl)purine; 2-Amino-6-chloropurineribonucleoside triacetate; 2',3',5'-Tri-O-acetyl-6-chloroguanosine; NSC 70388
  • Density:
  • 1.7g/cm3
  • Boiling Point:
  • 637°Cat760mmHg
  • Flash Point:
  • 339°C

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CAS No.16321-99-6 9H-Purin-2-amine,6-chloro-9-(2,3,5-tri-O-acetyl-b-D-ribofuranosyl)-

Assay:98.5%  Appearance:white or a...  Package:10g,100g,1kg

Supplier:Shanghai eliv pharmaceutical Co.,Ltd [ China (Mainland)]

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930Integral
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Tel:+86-21-50158063

Address:4th Floor 31building 300Chuantu Rd, Pudong new district, Shanghai,P.R China

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CAS No.16321-99-6 2-amino-6-chloropurine -2,3,5-triacetylriboside

500g,1kg,5kg

Supplier:Changzhou Wizard Chemical Co., Ltd. [ China (Mainland)]

610Integral
610

Tel:086-519-86531922

Address:Wujin industrial park Changzhou Jiangsu 213164 ,China

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Reference

Nucleic Acid Related Compounds
Nucleic Acid Related Compounds. 118. Nonaqueous Diazotization of Aminopurine Derivatives. Convenient Access to 6-Halo- and 2,6-Dihalopurine Nucleosides and 2'-Deoxynucleosides with Acyl or Silyl Halides. Francom, Paula; Robins, Morris J. (Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT 84602-5700, USA). Journal of Organic Chemistry, 68(2), 666-669 (English) 2003 American Chemical Society. CODEN: JOCEAH. ISSN: 0022-3263. DOCUMENT TYPE: Journal CA Section: 33 (Carbohydrates) Treatment of 9-(2,3,5-tri-O-acetyl-b-D-ribofuranosyl)-2-amino-6-chloropurine with TMS-Cl and benzyltriethylammonium nitrite (BTEA-NO2) in dichloromethane gave the cryst. 2,6-dichloropurine nucleoside I (R = OAc, X = Y = Cl), and acetyl chloride/BTEA-NO2 was equally effective (~85%, without chromatog.). TMS-Br/tert-Bu nitrite/dibromomethane gave cryst. 2-bromo-6-chloro analog I (R = OAc, X = Br, Y = Cl) (85%).Several substances are used for example 16321-99-6 which is its cas registry number. (Chloro or bromo)-dediazoniation of 3',5'-di-O-acetyl-2'-deoxyadenosine gave chloro I (R = X = H, Y = Cl) (63%) or bromo I (R = X = H, Y = Br) (80%) purine deoxynucleosides, and 2',3',5'-tri-O-acetyladenosine was converted into the 6-chloropurine nucleoside I (R = OAc, X = H, Y = Cl) (71%). .
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