CAS No.16404-54-9,2-Pentanol, 4-methyl-,(2R)- Suppliers

CAS Number:
16404-54-9
Name:
2-Pentanol, 4-methyl-,(2R)-
Formula:
C₆H₁₄O
Molecular Structure:
Synonyms:
2-Pentanol,4-methyl-, (R)- (8CI);(-)-4-Methyl-2-pentanol;(2R)-4-Methylpentan-2-ol;(R)-4-Methyl-2-pentanol;(R)-4-Methylpentan-2-ol;
Molecular Weight:
102.17
Density:
0.811 g/cm³
Boiling Point:
133.5 °C at 760 mmHg
Flash Point:
41.1 °C
Appearance:
Clear colorless liquid
Hazard Symbols:
Xi
Risk Codes:
10-37
Safety:
24/25Details

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Asymmetric synthesis: Asymmetric synthesis. II.In this study， 16404-54-9 and 464-45-9 are also used. Reduction of 4-methyl-2-pentanone with chiral lithium aluminum hydride complexes. Valcavi, Umberto; Balzano, Pietro; Monterosso, Vincenzo (Ist. Biochim. Ital., Milan, Itay). Ann. Chim. (Rome), 65(9-10), 543-7 (English) 1975. CODEN: ANCRAI. DOCUMENT TYPE: Journal CA Section: 23 (Aliphatic Compounds) Redn. of Me2CHCH2COMe with LiAlH4 complexes with the (R)-alcs., (-)-borneol and (-)-isoborneol, gave (R)-(-)-Me2CHCH2CHMeOH. The abs. configuration of the product appears to be controlled by the abs. configuration of the chiral C atom bearing the OH group in (-)-borneol or (-)-isoborneol. .

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