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Basic Information
CAS No.: 1646-88-4
Name: ALDICARB-SULFONE
Molecular Structure:
Molecular Structure of 1646-88-4 (ALDICARB-SULFONE)
Formula: C7H14 N2 O4 S
Molecular Weight: 222.265
Synonyms: Propionaldehyde,2-methyl-2-(methylsulfonyl)-, O-(methylcarbamoyl)oxime (7CI,8CI);Carbamicacid, methyl-, O-[[2-methyl-2-(methylsulfonyl)propylidene]amino] deriv. (8CI);2-Methyl-2-(methylsulfonyl)propionaldehyde O-(methylcarbamoyl)oxime;Aldicarbsulfone;Aldoxycarb;Standak;Sulfocarb;Temik sulfone;UC 21865;UCES;Yangdimiewei;
EINECS: 216-710-0
Density: 1.23g/cm3
Melting Point: 132-135 °C
Boiling Point: °Cat760mmHg
Flash Point: °C
Solubility: 10 g l-1 (25 °C)
Hazard Symbols:
Risk Codes: 24-26/28
Safety: Poison by ingestion, intraperitoneal, skin contact, and intravenous routes. When heated to decomposition it emits very toxic fumes of NOx and SOx. An insecticide.
PSA: 93.21000
LogP: 1.62310
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Chemistry

Molecular Structure of Aldoxycarb (CAS NO.1646-88-4):

IUPAC Name: [(E)-(2-methyl-2-methylsulfonylpropylidene)amino] N-methylcarbamate
Empirical Formula: C7H14N2O4
Molecular Weight: 222.2621 
Index of Refraction: 1.495 
Surface Tension: 40.1 dyne/cm
Density: 1.23 g/cm3 
Boiling Point: 132-135°C at 760 mmHg 
storage temp.:0-6°C
Synonyms of Aldoxycarb (CAS NO.1646-88-4): (1E)-2-Methyl-1-(([(methylamino)carbonyl]oxy)imino)-2-(methylsulfonyl)propane ; 2-mesyl-2-methylpropionaldehydeo-methylcarbamoyloxime ; 2-methyl-2-(methylsulfonyl)-propionaldehydo-(methylcarbamoyl)oxime;aldoxycarbe ; Carbamic acid, methyl-, O-[[2-methyl-2-(methylsulfonyl)propylidene]amino] deriv ; Propanal, 2-methyl-2-(methylsulfonyl)-, O-[(methylamino)carbonyl]oxime

Toxicity Data With Reference

1.    

orl-rat LD50:20 mg/kg

    TSCAT*    Office of Toxic Substances Report. (U.S. Environmental Protection Agency, Office of Toxics Substances, 401M Street SW, Washington, DC 20460) FYI-OTS-0885-0443 .
2.    

ihl-rat LC50:140 mg/m3/4H

    PEMNDP    Pesticide Manual. 9 (1991),18.
3.    

skn-rat LD50:1 g/kg

    SPEADM    Special Publication of the Entomological Society of America. 78-1 (1978),61.
4.    

ipr-rat LD50:21 mg/kg

    TSCAT*    Office of Toxic Substances Report. (U.S. Environmental Protection Agency, Office of Toxics Substances, 401M Street SW, Washington, DC 20460) FYI-OTS-0885-0443 .
5.    

ivn-rat LD50:14,900 µg/kg

    TSCAT*    Office of Toxic Substances Report. (U.S. Environmental Protection Agency, Office of Toxics Substances, 401M Street SW, Washington, DC 20460) FYI-OTS-0885-0443 .
6.    

skn-rbt LD50:200 mg/kg

    FMCHA2    Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1989,C14.
7.    

orl-dck LD50:33,500 µg/kg

    PEMNDP    Pesticide Manual. 9 (1991),18.

Safety Profile

Poison by ingestion, intraperitoneal, skin contact, and intravenous routes. When heated to decomposition it emits very toxic fumes of NOx and SOx. An insecticide.
 

Hazard Codes VeryT+
Risk Statements:24-26/28 
R24:Toxic in contact with skin. 
R26/28:Very toxic by inhalation and if swallowed.
Safety Statements:28-36/37-45 
R28:Very toxic if swallowed. 
R36/37:Irritating to eyes and respiratory system. 
R45:May cause cancer.
 

Specification

 Aldoxycarb (CAS NO.1646-88-4) is a highly toxic chemicals, flammable, while burning it would produce stimulating smoke, so it needed to be stored in low temperature, ventilation, drying and oxidability environmental condition, separated with food ingredients , water, carbon dioxide , dry powder, sand, water mist fire extinguishing can be used if urgency.