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| CAS No.: | 1668-10-6 |
|---|---|
| Name: | Glycinamide hydrochloride |
| Article Data: | 10 |
| Molecular Structure: | |
|
|
|
| Formula: | C2H6N2O.HCl |
| Molecular Weight: | 110.543 |
| Synonyms: | Acetamide,2-amino-, monohydrochloride (9CI);Glycinamide, monohydrochloride (8CI);Aminoacetamide hydrochloride;Glycine amide hydrochloride;H-Gly-NH2·HCl;H-Gly-NH2.HCl; |
| EINECS: | 216-789-1 |
| Density: | 1.122 g/cm3 |
| Melting Point: | 204 °C (dec.)(lit.) |
| Boiling Point: | 281.3 °C at 760 mmHg |
| Flash Point: | 123.9 °C |
| Solubility: | water: 0.1 g/mL, clear |
| Appearance: | Crystalline |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 36/37/38 |
| Safety: | 26-37/39 |
| PSA: | 69.11000 |
| LogP: | 0.63300 |
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- 5156-58-1N-(1-Benzyl-4-pipperidinyl)-N-phenylpropanamide HCl
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- 50288-62-5threo-Phenyl-2-piperidyl acetamide
- 82993-81-5D-threo-Ritalinic acid hydrochloride
- 47087-37-6Z-D-Glu-OMe
- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 211914-50-0N-[[2-[[[4-(Aminoiminomethyl)phenyl]amino]methyl]-1-methyl-1H-benzimidazol-5-yl]carbonyl]-N-(2-pyridinyl)-beta-alanine ethyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With hydrogenchloride; 2-hydroxyethanethiol In tetrahydrofuran at -78℃; | 86% |
| Conditions | Yield |
|---|---|
| With ammonia In ethanol at 100℃; for 0.5h; | 76% |
- 141509-41-3
4-methylene-1-oxa-6,9-diazaspiro<4,5>decane-7,10-dione
A
- 1668-10-6
glycinamide hydrochloride
B
- 114533-59-4
3-hydroxy-4-(2-hydroxyethyl)-2(5H)-furanone
| Conditions | Yield |
|---|---|
| With hydrogenchloride at 100℃; for 1.5h; Product distribution; other conditions, other reagents; | A 33% B 56% |
- 1668-10-6
glycinamide hydrochloride
| Conditions | Yield |
|---|---|
| bei dreiwoechigem Aufbewahren; |
| Conditions | Yield |
|---|---|
| With ammonia In methanol for 72h; Ambient temperature; |
- 1668-10-6
glycinamide hydrochloride
- 1148-11-4
N-Benzyloxycarbonyl-L-proline
- 35010-96-9
Nα-benzyloxycarbonyl-L-prolyl-glycinamide
| Conditions | Yield |
|---|---|
| With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; | 100% |
| Stage #1: N-Benzyloxycarbonyl-L-proline With 1,1'-carbonyldiimidazole In tetrahydrofuran at 20℃; Stage #2: glycinamide hydrochloride With triethylamine In tetrahydrofuran at 20℃; Further stages.; | 53% |
| With 4-methyl-morpholine; isobutyl chloroformate 1) DMF, -15 deg C, 15 min, 2) -10 deg C, 14h; Yield given. Multistep reaction; |
- 1668-10-6
glycinamide hydrochloride
- 60379-01-3
N-(benzyloxycarbonyl)-L-phenylalanine benzyl ester
- 17187-05-2
Z-L-phenylalanylglycinamide
| Conditions | Yield |
|---|---|
| With S166C-SBnCOOH; triethylamine; calcium chloride In water; N,N-dimethyl-formamide for 1h; Ambient temperature; | 100% |
| With triethylamine; enzyme mutant SBL-S166C-S-[(4S,5R)-indenooxazolidinonyl] In water; N,N-dimethyl-formamide at 20℃; for 1h; pH=5.8; | 100% |
| With triethylamine; S166C-S-S-(CH2)2-O-β-D-Glc(Ac)2 subtilisin protease In water; N,N-dimethyl-formamide at 20℃; for 1h; pH=5.8; Enzymatic reaction; MES buffer; | 95% |
| With subtilisin BPN'; triethylamine In water; N,N-dimethyl-formamide Ambient temperature; | 80% |
| Conditions | Yield |
|---|---|
| With S166C-SCH2CH2NH3+; triethylamine; calcium chloride In water; N,N-dimethyl-formamide for 5h; Ambient temperature; | 100% |
| With triethylamine; enzyme mutant SBL-S166C-S-CH2C(CH2NH3)3 In water; N,N-dimethyl-formamide at 20℃; for 5h; pH=5.8; | 71% |
| With triethylamine; S166C-S-S-(CH2)2-O-β-D-Gal subtilisin protease In water; N,N-dimethyl-formamide at 20℃; for 5h; pH=5.8; Enzymatic reaction; MES buffer; | 67% |
- 1668-10-6
glycinamide hydrochloride
- 82911-69-1
N-(9H-fluoren-2-ylmethoxycarbonyloxy)succinimide
- 115057-37-9
Fmoc-Gly-NH2
| Conditions | Yield |
|---|---|
| With sodium carbonate In acetone at 20℃; for 1h; | 100% |
| With sodium hydrogencarbonate In acetone at 20℃; for 2h; pH=7; | 80% |
| With sodium carbonate In water; acetone at 0 - 20℃; for 1.5h; | 72% |
- 912773-22-9
6-bromopyrazolo[1,5-a]pyrimidine-3-carboxylic acid
- 1668-10-6
glycinamide hydrochloride
- 1065082-89-4
N-(2-amino-2-oxoethyl)-6-bromopyrazolo[1,5-a]pyrimidine-3-carboxamide
| Conditions | Yield |
|---|---|
| With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; triethylamine In N,N-dimethyl-formamide at 20℃; for 2h; | 100% |
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Chemistry
IUPAC Name: 2-Aminoacetamide hydrochloride
Molecular Formula: C2H7ClN2O
Molecular Weight:110.542780 g/mol
Appearance: White to off-white solid
Water solubility: 0.1 g/mL, clear
BRN: 3554199
Density: 1.122g/cm3
Melting Point: 204 oC
Flash Point: 123.9°C
storage temp.: Store at RT.
Index of Refraction: 1.469
Surface Tension: 49.1 dyne/cm
Enthalpy of Vaporization: 52.01 kJ/mol
Boiling Point: 281.3 °C at 760 mmHg
Vapour Pressure: 0.00359 mmHg at 25 °C
Synonyms of Glycinamide Hydrochloride(1668-10-6):
h-Gly-nh2 hcl;glycinamide hcl ; Glycinamide hydrochloride ; Glycine-nh2 hcl;glycine amide hydrochloride ; Gly-nh2 hydrochloride ; 2-Aminoacetamide hydrochloride ; Glycinamide monohydrochloride
Categories of Glycinamide Hydrochloride(1668-10-6):
Amino Acid Derivatives;(intermediate of oxiracetam);Amino Acids;Glycine [Gly, G];Amino Acids and Derivatives;Amino hydrochloride;Amides;Carbonyl Compounds;Organic Building Blocks;A - HOrganic Building Blocks;Amino Acids;Modified Amino Acids
Uses
Glycinamide Hydrochloride(1668-10-6) is used as a pharmaceutical intermediate,also used in the organic synthesis.
Safety Profile
Safety Information of Glycinamide Hydrochloride(1668-10-6):
Hazard Codes:Xi 
Risk Statements:36/37/38
36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements:22-24/25-37/39-26
22:Do not breathe dust
24/25:Avoid contact with skin and eyes
37/39:Wear suitable gloves and eye/face protection
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
WGK Germany:3
F:3-10
HS Code:29241900
Specification
First Aid Measures of Glycinamide Hydrochloride(1668-10-6):
Ingestion:Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin:Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Storage of Glycinamide Hydrochloride(1668-10-6):
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.