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Detail of "16903-61-0"

  • CAS Number:
  • 16903-61-0
  • Name:

  • Copper,[tetrahydroborato(1-)-kH,kH']bis(triphenylphosphine)-,(T-4)-

  • Superlist Name:
  • Bis-(triphenylphosphino)-cuprous borohydride
  • Molecular Structure:
  • Formula:
  • 2(C18H15P).Cu.BH4
  • Molecular Weight:
  • 602.97
  • Synonyms:
  • Copper,(tetrahydroborato)bis(triphenylphosphine)- (7CI);Copper, [tetrahydroborato(1-)-H,H']bis(triphenylphosphine)-,(T-4)-;Copper, [tetrahydroborato(1-)]bis(triphenylphosphine)- (8CI);(Tetrahydroborato)bis(triphenylphosphine)copper;Bis(triphenylphosphine)copper(I) borohydride;Bis(triphenylphosphine)cuprousborohydride;Tetrahydroboratobis(triphenylphosphine)copper(I);[Tetrahydroborato(1-)]bis(triphenylphosphine)copper;
  • EINECS:
  • 240-951-0
  • Melting Point:
  • 164 °C (dec.)(lit.)
  • Boiling Point:
  • 360 °C at 760 mmHg
  • Flash Point:
  • 181.7 °C
  • Hazard Symbols:
  • IrritantXi
  • Risk Codes:
  • 36/37/38
  • Safety:
  • 26 Details
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CAS No.16903-61-0 Bis-(triphenylphosphino)-cuprous borohydride

Supplier:Hangzhou Dayangchem Co., Ltd. [ China (Mainland)]

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Address:B/2601 Fuli Building, 328# WenEr Rd. Hangzhou City 310012 China

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CAS No.16903-61-0 Bis-(triphenylphosphino)-cuprous borohydride

Name：Bis(triphenylposphine) coppor(I)tetrahydroborate CAS Number：16903-61-0 Molecular Formula：C36H34BCuP2 Molecular Weight：602.96

Supplier:Beijing Chunpu Center of Application Technology [ China (Mainland)]

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Tel:861082572604

Address:beijing

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CAS No.16903-61-0 Bis-(triphenylphosphino)-cuprous borohydride

Bis-(triphenylphosphino)-cuprous borohydride

Supplier:TRUST&WE CO.,Ltd. [ China (Mainland)]

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Address:No. 317, 219 Nong, Gao Muqiao Road, Zhangjiang Hightech. Park, Pudong, Shanghai

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CAS No.16903-61-0 Bis-(triphenylphosphino)-cuprous borohydride

Bis(triphenylphosphine)copper Tetrahydroborate

Supplier:Suzhou Sinocompound Technology Co., Ltd. [ China (Mainland)]

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Tel:+86-512-68326260

Address:Room 426 No.1326,Binhe Road,Suzhou New District,Jiangsu,P.R.China

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CAS No.16903-61-0 Bis-(triphenylphosphino)-cuprous borohydride

Supplier:Beijing zhongke expanding chemical technology Co., LTD. [ China (Mainland)]

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Tel:010-51600645 58608265；57131961

Address:Beijing changping area connects center north pearl tower 2 buildings

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Reference

Metal-promoted trimerization of carbon disulfide
Metal-promoted trimerization of carbon disulfide. Synthesis and structure of the dinuclear copper(I) complex [(PPh3)2Cu(m-S2CSCH2SCS2)Cu(PPh3)2]. Bianchini, Claudio; Ghilardi, Carlo A.; Meli, Andrea; Midollini, Stefano; Orlandini, Annabella (Ist. Stud. Stereochim. Energ. Composti Coord., CNR, Florence 50132, Italy). J. Chem. Soc., Chem. Commun., (9), 545-6 (English) 1983. CODEN: JCCCAT. ISSN: 0022-4936. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) Section cross-reference(s): 75 Reaction of [(Ph3P)2Cu(h2-BH4)] with CS2 in CH2Cl2 gave [(Ph3P)2Cu(m-S2CSCH2SCS2)Cu(PPh3)2] (I). Crystals of I are monoclinic, space group C2/c, with a 53.573(30), b 12.759(9), c 22. 16903-61-0 and 75-15-0 which are cas registry numbers of chemicals are mentioned.856(15) ?, b 104.6(1)°, U 15119.1 ?3, Z = 8, d.(calcd.) = 1.236 g cm-3, and R = 0.092. The 2 (Ph3P)2Cu fragments are held together by a bridging S2CSCH2SCS22- ligand formed by double head-to-tail condensation of 3 CS2 mols. .
Reactions of tetrahydrogenoboratebis(triphenylphosphine)copper(I) complex with nitrophenols
Reactions of tetrahydrogenoboratebis(triphenylphosphine)copper(I) complex with nitrophenols. Naldini, L.; Panzanelli, A.; Rassu, G.; Cariati, F.; Demartin, F.; Manassero, M.; Masciocchi, N. (Ist. Chim. Gen., Univ. Sassari, Sassari 07100, Italy). Inorg. Chim. Acta, 83(3), L71-L73 (English) 1984. CODEN: ICHAA3. ISSN: 0020-1693. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) Section cross-reference(s): 75 Cu(PPh3)2(BH4) reacted with nitrophenols in EtOH or THF to give Cu(PPh3)2L (I) (HL = 2-NO2C6H4OH, 2,4-, 2,5-, and 2,6-(NO2)2C6H3OH, 2,4,6-(NO2)3C6H2OH) and Cu2(PPh3)3(OC6H4NO2-4)2 (II). I (HL = 2-NO2C6H4OH) is monoclinic, space group P21/n, with a 14.355(3), b 16.073(2), c 16.128(3) ?, b 107.75(2), Z = 4, d.(calcd.) = 1.36 g cm-3. I (HL = 2,4-(NO2)2C6H3OH) is triclinic, space group P1, with a 13.351(3), b 13.386(2), c 13.050(2) ?, a 115.96(2), b 90.99(2), g 112.95(2)°, Z = 2, d.(calcd.) = 1.36 g cm-3. II is monoclinic, space group P21/c, with a 15.184(3), b 38.506(13), c 19. 89947-39-7 and 16903-61-0 which are cas registry numbers of substances are two of reagents here.921(5) ?, b 98.69(2)°, Z = 8, d.(calcd.) = 1.37 g cm-3. In II both dinitrophenolates are bidentate bridging, 2 PPh3 ligands coordinate 1 Cu atom and the 3rd PPh3 coordinates the other Cu atom. I and II were characterized by IR spectra. .
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