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16919-27-0

Basic Information
CAS No.: 16919-27-0
Name: Potassium hexafluorotitanate
Molecular Structure:
Molecular Structure of 16919-27-0 (Potassium hexafluorotitanate)
Formula: F6K2Ti
Molecular Weight: 240.04 .
Synonyms: Dipotassium monotitanium hexafluoride;Dipotassiumtitanium hexafluoride;NSC 187663;NSC 43605;Potassium hexafluorotitanate (K2TiF6);Titanate(2-), hexafluoro-, dipotassium,(OC-6-11)- (9CI);
EINECS: 240-969-9
Density: 3.01
Melting Point: 780 °C
Boiling Point: 235-237°C
Flash Point: 235-237°C
Solubility: Soluble in hot water. Slightly soluble in cold water and inorganic acid. Insoluble in ammonia.
Appearance: White Crystalline Powder
Hazard Symbols: HarmfulXn
Risk Codes: 22-41-43
Safety: 26-36/37/39
PSA: 0.00000
LogP: 2.52120
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Chemistry

IUPAC Name: dipotassium hexafluorotitanium(2-)
Molecular Formula: F6K2Ti
Molecular Weight: 240.05
EINECS: 240-969-9 
Structure of Titanate(2-),hexafluoro-, potassium (1:2), (OC-6-11)- (CAS NO.16919-27-0):
Melting point:  780°C
Flash point:  235-237°C
Enthalpy of Vaporization: 25.54 kJ/mol 
Boiling Point: 19.5 °C at 760 mmHg 
Vapour Pressure: 922 mmHg at 25°C 
Product Categories: Inorganics;Catalysis and Inorganic Chemistry;Metal and Ceramic Science;Potassium SaltsChemical Synthesis;Salts;Titanium 
Canonical SMILES: F[Ti-2](F)(F)(F)(F)F.[K+].[K+]
InChI: InChI=1S/6FH.2K.Ti/h6*1H;;;/q;;;;;;2*+1;+4/p-6
InChIKey: RXCBCUJUGULOGC-UHFFFAOYSA-H

Uses

 Titanate(2-),hexafluoro-, potassium (1:2), (OC-6-11)- (16919-27-0) is mainly used as analytical reagents, also used in the manufacture of titanium acid and titanium.

Toxicity Data With Reference

1.    

scu-frg LDLo:360 mg/kg

    CRSBAW    Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. 124 (1937),133.


RTECS:  TT1575000

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by subcutaneous route. When heated to decomposition it emits toxic fumes of K2O and F.
Hazard Codes: HarmfulXn
Risk Statements:  22-41-43
R22:Harmful if swallowed.
R41:Risk of serious damage to the eyes. 
R43:May cause sensitization by skin contact.
Safety Statements:  26-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
RIDADR:  3288
WGK Germany:  2
HazardClass:  6.1
PackingGroup:  III

Standards and Recommendations

OSHA PEL: TWA 2.5 mg(F)/m3
ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
NIOSH REL: TWA 2.5 mg(F)/m3

Specification

 Titanate(2-),hexafluoro-, potassium (1:2), (OC-6-11)- (16919-27-0) is also named as Dipotassium hexafluorotitanate ; 
 Potassium titanium fluoride ; Titanium potassium fluoride ; Dipotassium hexafluorotitanate(2-) ; Fluotitanate de potassium [French] ; Potassium fluorotitanate (K2TiF6) , and so on . Potassium hexafluorotitanate(16919-27-0) is colorless monoclinic lamellae.