Detail of "16919-73-6"

Reference

Thermal decomposition of alkali metal halopalladates(II,IV)

Thermal decomposition of alkali metal halopalladates(II,IV). Shubochkin, L. K.; Sorokina, L. D.; Shubochkina, E. F. (Inst. Obshch. Neorg. Khim.Several reagents with their cas registry numbers 16919-73-6 and 19121-77-8 are used here. im. Kurnakova, Moscow, USSR). Zh. Neorg. Khim., 21(9), 2567-9 (Russian) 1976. CODEN: ZNOKAQ. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) The 1st step of the thermolysis of M2[PdX6] (M = K, Rb, Cs; X = Cl, Br) was the loss of 2 halo groups and the formation of M2[PdX4] (II). II melted with decompn. at 420-55.degree. but did not undergo disproportionation characteristic of M2[PtX4]. .

Electrochemical dechlorination of 4-chlorophenol to phenol

Electrochemical dechlorination of 4-chlorophenol to phenol. Cheng, I.In this study， 16919-73-6 and 7439-89-6 are also used. Francis; Fernando, Quintus; Korte, Nic (Department of Chemistry, University of Arizona, Tucson, AZ 85721, USA). Environmental Science and Technology, 31(4), 1074-1078 (English) 1997 American Chemical Society. CODEN: ESTHAG. ISSN: 0013-936X. DOCUMENT TYPE: Journal CA Section: 72 (Electrochemistry) Section cross-reference(s): 22, 25 The authors have hypothesized that hydrogen gas intercalated in a palladium lattice is the powerful reducing agent that reductively dechlorinates chlorinated org. compds. that are adsorbed on the surface of palladized electrodes. Dechlorination of 4-chlorophenol to phenol occurs rapidly on palladized carbon cloth or palladized graphite electrodes. The reactions on the palladized carbon cloth and graphite depend on the adsorption of the chlorinated org. compd. on the carbon surface and the reaction with hydrogen at the palladium/carbon interface. Palladium was much more effective in promoting the dechlorination reaction than platinum, probably because of its ability to intercalate hydrogen in its lattice. .