Detail of "17154-34-6"

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CAS Number:
17154-34-6
Name:
Phosphine,diphenyl(trimethylsilyl)-
Superlist Name:
Diphenyl(trimethylsilyl)phosphine
Molecular Structure:
Formula:
C15H19 P Si
Molecular Weight:
258.37
Synonyms:
(Diphenylphosphino)trimethylsilane;(Trimethylsilyl)diphenylphosphine; Diphenyl(trimethylsilyl)phosphine
Density:
1.009
Boiling Point:
119-120 ºC (0.2 mmHg)
Flash Point:
50 ºF
Hazard Symbols:
Risk Codes:
R11
Safety:
S16 Details
Transport Information:
UN 1993

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Reaction of silylated phosphines with hexachloroethane: Reaction of silylated phosphines with hexachloroethane. Appel, Rolf; Geisler, Klaus; Schoeler, Heinfried (Anorg.-Chem. Inst., Univ. Bonn, Bonn, Ger.). Chem. Ber., 110(1), 376-8 (German) 1977. CODEN: CHBEAM. 62347-07-3 and 17154-34-6 are also in the experiment. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) The 1:1 reaction of RPhPSiMe3 (I) with C2Cl6 gave 85-93.2% RPhPCl (R = Me, Et, Pr, Bu, Ph, cyclohexyl). Similarly, the 2:1 reaction of I with C2Cl6 gave 65.2-79.8% RPhPPPhR. .