Detail of "173792-58-0"

CAS Number:
173792-58-0
Name:
2(5H)-Furanone,3-methyl-5-[(7E,9R,10R,12R,15S,16E,17aS,21aR)-2,3,5,6,9,10,11,12,13,14,15,17a,20,21-tetradecahydro-15-hydroxy-8,10,16,18-tetramethyl-9,12-epoxy-1H-benzo[2,3]cyclohexadeca[1,2-b]pyridin-19-yl]-,(5S)-
Molecular Structure:
Formula:
C32H45 N O4
Molecular Weight:
507.704
Synonyms:
2(5H)-Furanone,3-methyl-5-(2,3,5,6,9,10,11,12,13,14,15,17a,20,21-tetradecahydro-15-hydroxy-8,10,16,18-tetramethyl-9,12-epoxy-1H-benzo[2,3]cyclohexadeca[1,2-b]pyridin-19-yl)-,[9R-[7E,9R*,10R*,12R*,15S*,16E,17aS*,19(S*),21aR*]]-; (-)-Gymnodimine;Gymnodimine; Gymnodimine A
Density:
1.23g/cm³
Boiling Point:
672.1°Cat760mmHg
Flash Point:
360.3°C

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Studies toward a Marine Toxin Immunogen: Enantioselective Synthesis of the Spirocyclic Imine of (-)-Gymnodimine: Studies toward a Marine Toxin Immunogen: Enantioselective Synthesis of the Spirocyclic Imine of (-)-Gymnodimine. Kong, Ke; Moussa, Ziad; Romo, Daniel (Department of Chemistry, Texas A&M University, College Station, TX 77842-3012, USA). Organic Letters, 7(23), 5127-5130 (English) 2005 American Chemical Society. CODEN: ORLEF7. ISSN: 1523-7060. DOCUMENT TYPE: Journal CA Section: 26 (Biomolecules and Their Synthetic Analogs) An enantioselective Diels-Alder reaction catalyzed by an Evans' copper-bis(oxazoline) complex was utilized to construct highly functionalized spirolactam I, a key intermediate in our projected total synthesis of the marine toxin, gymnodimine (II). Addnl. transformations, including a mild N-tosyl group deprotection, afforded a keto spirocyclic imine moiety III, the proposed pharmacophore of gymnodimine. Thus, the prepd. ketone is a potentially useful intermediate for conjugation to provide an immunogen for eventual monitoring of gymnodimine and congeners. 173792-58-0 which is the cas registry number of one of substances is just one of reagents here. .Some commonly used reagents like 173792-58-0 is used in this experiment..

Studies toward a Marine Toxin Immunogen: Enantioselective Synthesis of the Spirocyclic Imine of (-)-Gymnodimine: Studies toward a Marine Toxin Immunogen: Enantioselective Synthesis of the Spirocyclic Imine of (-)-Gymnodimine. Kong, Ke; Moussa, Ziad; Romo, Daniel (Department of Chemistry, Texas A&M University, College Station, TX 77842-3012, USA). Organic Letters, 7(23), 5127-5130 (English) 2005 American Chemical Society. CODEN: ORLEF7. ISSN: 1523-7060. DOCUMENT TYPE: Journal CA Section: 26 (Biomolecules and Their Synthetic Analogs) An enantioselective Diels-Alder reaction catalyzed by an Evans' copper-bis(oxazoline) complex was utilized to construct highly functionalized spirolactam I, a key intermediate in our projected total synthesis of the marine toxin, gymnodimine (II). Addnl. transformations, including a mild N-tosyl group deprotection, afforded a keto spirocyclic imine moiety III, the proposed pharmacophore of gymnodimine. Thus, the prepd. ketone is a potentially useful intermediate for conjugation to provide an immunogen for eventual monitoring of gymnodimine and congeners. 173792-58-0 which is the cas registry number of one of substances is just one of reagents here. .Some commonly used reagents like 173792-58-0 is used in this experiment..