Detail of "1778-09-2"

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CAS Number:
1778-09-2
Name:
Ethanone,1-[4-(methylthio)phenyl]-
Superlist Name:
4'-Methylthioacetophenone
Molecular Structure:
Formula:
C₉H₁₀OS
Molecular Weight:
166.24
Synonyms:
Acetophenone,4'-(methylthio)- (6CI,7CI,8CI);1-[4-(Methylthio)phenyl]ethanone;4-Acetylphenyl methyl sulfide;4-Acetylthioanisole;Methyl4-(methylthio)phenyl ketone;Methyl p-acetylphenyl sulfide;p-(Methylmercapto)acetophenone;p-Acetylphenylmethyl sulfide;p-Acetylthioanisole;
EINECS:
217-213-1
Density:
1.1 g/cm³
Melting Point:
80-82 °C(lit.)
Boiling Point:
282.5 °C at 760 mmHg
Flash Point:
140.7 °C
Appearance:
White to light yellow crystal powder
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety:
26-36 Details
particular:
particular

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Homogeneous catalysis in the Cr(V) oxidation of organic sulfides: Homogeneous catalysis in the Cr(V) oxidation of organic sulfides.Several substances are used for example 70132-29-5 and 1778-09-2 which are their cas registry numbers. Bharathy, Jesuraja Bosco; Ganesan, Tharumeya Kuppusamy; Sheriff, Ambalam Ibrahim Ali Mohammed; Rajagopal, Seenivasan (Dep. Chemistry, The American College, Madurai 625 002, India). Tetrahedron, 53(3), 1131-1144 (English) 1997 Elsevier. CODEN: TETRAB. ISSN: 0040-4020. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Pyridine bases picolinic acid, 2,2'-bipyridyl and 1,10-phenanthroline, imidazole and N-methylimidazole efficiently catalyze the carboxylato-bound Cr(V) oxidn. of aryl Me sulfides. The catalysis is explained in terms of intermediate Cr(V)-catalyst and Cr(V)-catalyst-substrate complexes. The products, sulfoxide and Cr(III), are formed due to ligand coupling of O and the S center of sulfide. The catalyzed Cr(V) oxidn. of org. sulfides is in accordance with the reactivity-selectivity principle. .

Thermal printing material using cyclohexenoyl ester as color developer: Shibata, Mitsuru (Idemitsu Kosan Co., Ltd., Japan). Jpn. Kokai Tokkyo Koho JP 2004106447 A2 8 Apr 2004, 54 pp. (Japanese). (Japan). CODEN: JKXXAF.In this article, certain chemicals are used. One of their cas registry numbers is 1778-09-2 CLASS: ICM: B41M005-30. ICS: C07C069-24; C07C069-83; C07C069-92; C07C317-44. APPLICATION: JP 2002-274846 20 Sep 2002. DOCUMENT TYPE: Patent CA Section: 74 (Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes) Compds. I and II [X2 = C8-18 alkyl, C3-6 cycloalkyl, C2-4 alkenyl, C2-4 alkynyl, CONR14R15, NHCO2R13, NHCONHR15, NHCOSR15, NHSO2R15, OCOR15, SOq(CH2)mCONHSO2(CH2)k(NHCONH)jR15, etc.; A = O, S, SO, SO2 CR16R17, CO, CH2CH2, NHCONH, NH(C:S)NH; R13, R16-17 = C1-4 alkyl, haloalkyl; R14 = C1-4 alkyl, C1-4 haloalkyl, halo, Ph which may be substituted with alkyl or haloalkyl; R15 = C1-18 alkyl, halo, Ph which may be substituted with alkyl or haloalkyl; m = 1-4; k = 1-6; j = 0,1; q = 0-2] are claimed. The material comprises a support coated with a heat-sensitive layer contg. a colorless or pale colored dye and a color developer bearing 31 structure Q1 (R1-R6 = H, C1-4 alkyl, C1-4 haloalkyl, Ph substituted with C1-4 alkyl or halo). The compd. shows good color developability using less amt. and formed image shows good chem. and oil resistance, and the compd. is also useful as acid generator in polymn. catalyst, curing agent and photosensitive image forming material, etc. .

Detail of "1778-09-2"

Ethanone,1-[4-(methylthio)phenyl]-

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