CAS No.1826-67-1,Magnesium,bromoethenyl- Suppliers,MSDS download

Detail of "1826-67-1"

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CAS Number:

1826-67-1

Name:

Magnesium,bromoethenyl-

Superlist Name:

Vinylmagnesium bromide

Molecular Structure:

Formula:

C₂H₃BrMg

Molecular Weight:

131.25

Synonyms:

Magnesium,bromovinyl- (7CI,8CI);Vinylmagnesium bromide (6CI);Bromovinylmagnesium;Ethenylmagnesium bromide;Norman reagent;

EINECS:

217-375-3

Density:

0.981 g/mL at 25 °C

Flash Point:

-17 °C

Solubility:

vigorous reaction with water

Appearance:

Clear light brown to brown solution

Hazard Symbols:

Risk Codes:

11-14-19-34-14/15

Safety:

16-26-29-33-36/37/39-45-6A-43B Details

Transport Information:

UN 3399 4.3/PG 2

Reference

Synthesis and conformational analysis of fructose-derived scaffolds: molecular diversity from a single molecule: Synthesis and conformational analysis of fructose-derived scaffolds: molecular diversity from a single molecule. Cipolla, Laura; Forni, Eleonora; Jimenez-Barbero, Jesus; Nicotra, Francesco (Dipartimento di Biotecnologie e Bioscienze Universita degli Studi di Milano-Bicocca, Milan 20126, Italy). Chemistry--A European Journal, 8(17), 3976-3983 (English) 2002 Wiley-VCH Verlag GmbH & Co. KGaA. CODEN: CEUJED. ISSN: 0947-6539. DOCUMENT TYPE: Journal CA Section: 33 (Carbohydrates) Section cross-reference(s): 22 Bi- and tricyclic compds. were synthesized starting from fructose.Chemical with cas number 326487-08-5 also plays role. The different hydroxyl groups present in fructose were exploited in the formation of a no. of conformationally constrained sugar-based scaffolds, including azido acids. Introduction of an azido group and carboxy terminus into different bicyclic iodo ethers, allowed the synthesis of different conformationally constrained azido acids. Conformational anal. of the constrained C-glycosides were studied by NMR expts. assisted by mol. mechanics, allowed the detn. of the distances between the relevant functional groups, that is the azido and carboxy functionalities.Except for chemicals metioned above, 111085-83-7 and 1826-67-1 are also used. ..

Synthesis of 7-formylindole using the Bartoli indole methodology: Synthesis of 7-formylindole using the Bartoli indole methodology. Dobson, David R.; Gilmore, Jeremy; Long, David A. (Chem. Dep., Eli Lilly and Co. Ltd., Windlesham/Surrey GU20 6PH, UK). Synlett, (1), 79-80 (English) 1992. CODEN: SYNLES. ISSN: 0936-5214. DOCUMENT TYPE: Journal CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) The Bartoli methodol. provides a convenient synthetic route to 7-formylindole (I), either indirectly, via an improved metalation of 7-bromoindole using sodium hydride/butyllithium or two equiv. of butyllithium, or directly, by use of an acetal protected 2-nitrobenzaldehyde and vinylmagnesium bromide. 48140-35-8 and 1826-67-1 are just another two chemicals used in this study. Thus, 2-[(BuO)2CH]C6H4NO2 was treated with CH2:CHMgBr and then HCl-THF to give I in a 68% overall yield. .

Detail of "1826-67-1"

Magnesium,bromoethenyl-

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CAS No.1826-67-1 Vinylmagnesium bromide

CAS No.1826-67-1 Vinylmagnesium bromide

CAS No.1826-67-1 Vinylmagnesium bromide

CAS No.1826-67-1 Vinylmagnesium bromide

CAS No.1826-67-1 Vinylmagnesium bromide

CAS No.1826-67-1 Vinylmagnesium bromide

CAS No.1826-67-1 Vinylmagnesium bromide

Reference