Detail of "18881-17-9"

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CAS Number:
18881-17-9
Name:
3-Isoquinolinemethanol,1,2,3,4-tetrahydro-, (3S)-
Superlist Name:
(S)-(-)-1,2,3,4-Tetrahydro-3-isoquinolinemethanol
Molecular Structure:
Formula:
C₁₀H₁₃NO
Molecular Weight:
163.22
Synonyms:
3-Isoquinolinemethanol,1,2,3,4-tetrahydro-, (S)- (8CI);(S)-(1,2,3,4-Tetrahydroisoquinolin-3-yl)methanol;(S)-1,2,3,4-Tetrahydro-3-isoquinolinemethanol;(S)-3-Hydroxymethyl-1,2,3,4-tetrahydroisoquinoline;
Density:
1.082 g/cm³
Melting Point:
114-116 °C(lit.)
Boiling Point:
307.935 °C at 760 mmHg
Flash Point:
146.97 °C
Appearance:
white to light yellow crystal powder
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety:
26-36-37/39 Details

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CAS No.18881-17-9 (S)-(-)-1,2,3,4-Tetrahydro-3-isoquinolinemethanol

(3S)-1,2,3,4-tetrahydroisoquinolin-3-ylmethanol

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(3S)-1,2,3,4-tetrahydroisoquinolin-3-ylmethanol

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(3S)-1,2,3,4-tetrahydroisoquinolin-3-ylmethanol Tic-ol 18881-17-9

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Reference

Enantioselective catalytic borane reductions of aromatic ketones: syntheses and application of two chiral b-amino alcohols from (S)-porretine: Enantioselective catalytic borane reductions of aromatic ketones: syntheses and application of two chiral b-amino alcohols from (S)-porretine. Stingl, Klaus; Martens, Juergen; Wallbaum, Sabine (Fachbereich Chem., Univ. Oldenburg, Oldenburg D-2900, Germany). Tetrahedron: Asymmetry, 3(2), 223-6 (English) 1992. CODEN: TASYE3. ISSN: 0957-4166. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) The in situ formed chiral oxazaborolidine catalysts from two optically active b-amino alcs. 18881-17-9 and 14044-65-6 which are cas registry numbers are also used here. (S)-I (R = H, Ph) from benzyl (S)-1,2,3,4-tetrahydroisoquinoline-3-carboxylate were successfully used in the enantioselective catalytic homogeneous borane redns. of various arom. ketones. Thus, enantioselective redn. of acetophenone with BH3×THF complex/I (R = Ph) in THF followed by acidic workup gave 51% optical yield of (R)-1-phenylethanol. .

Detail of "18881-17-9"

3-Isoquinolinemethanol,1,2,3,4-tetrahydro-, (3S)-

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CAS No.18881-17-9 (S)-(-)-1,2,3,4-Tetrahydro-3-isoquinolinemethanol

CAS No.18881-17-9 (S)-(-)-1,2,3,4-Tetrahydro-3-isoquinolinemethanol

CAS No.18881-17-9 (S)-(-)-1,2,3,4-Tetrahydro-3-isoquinolinemethanol

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CAS No.18881-17-9 (S)-(-)-1,2,3,4-Tetrahydro-3-isoquinolinemethanol

CAS No.18881-17-9 (S)-(-)-1,2,3,4-Tetrahydro-3-isoquinolinemethanol

CAS No.18881-17-9 (S)-(-)-1,2,3,4-Tetrahydro-3-isoquinolinemethanol

CAS No.18881-17-9 (S)-(-)-1,2,3,4-Tetrahydro-3-isoquinolinemethanol

CAS No.18881-17-9 (S)-(-)-1,2,3,4-Tetrahydro-3-isoquinolinemethanol

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