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| CAS No.: | 19231-06-2 |
|---|---|
| Name: | bis(p-methoxyphenyl)iodonium bromide |
| Article Data: | 5 |
| Molecular Structure: | |
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| Formula: | C14H14BrIO2 |
| Molecular Weight: | 421.072 |
| Synonyms: | Iodonium,bis(4-methoxyphenyl)-, bromide (9CI);Iodonium, bis(p-methoxyphenyl)-, bromide(8CI);Bis(4-methoxyphenyl)iodonium bromide;Bis(p-anisyl)iodonium bromide;Di(p-Anisyl)iodonium bromide;NSC 141350;p,p'-Dimethoxydiphenyliodoniumbromide; |
| EINECS: | 242-899-4 |
| Density: | 1.82[at 20℃] |
| Melting Point: | 190-192 °C |
| Solubility: | 2.3mg/L at 20℃ |
| PSA: | 18.46000 |
| LogP: | -3.16380 |
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Specification
The CAS registry number of Iodonium,bis(4-methoxyphenyl)-, bromide (1:1) is 19231-06-2. Its EINECS registry number is 242-899-4. The IUPAC name is bis(4-methoxyphenyl)iodanium bromide. In addition, the molecular formula is C14H14BrIO2 and the molecular weight is 421.07. It is also called p,p'-dimethoxydiphenyliodoniumbromide. What's more, it should be stored in a cool and dry place.
Physical properties about this chemical are: (1)#H bond acceptors:2; (2)#Freely Rotating Bonds:4; (3)Polar Surface Area:18.46 Å2; (4)H-Bond Acceptor: 3; (5)Rotatable Bond Count: 4; (6)Exact Mass: 419.922185; (7)MonoIsotopic Mass: 419.922185; (8)Topological Polar Surface Area: 18.5; (9)Heavy Atom Count: 18; (10)Complexity: 184; (11)Covalently-Bonded Unit Count: 2.
Uses of Iodonium,bis(4-methoxyphenyl)-, bromide (1:1): it can be used to get iodobenzene. This reaction will need reagent actived zinc dust, catalyst Pd(acac)2 and solvent tetrahydrofuran. The reaction time is 10 minutes with ambient temperature. The yield is about 82%.
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You can still convert the following datas into molecular structure:
(1)SMILES: [Br-].[I+](c1ccc(OC)cc1)c2ccc(OC)cc2
(2)InChI: InChI=1/C14H14IO2.BrH/c1-16-13-7-3-11(4-8-13)15-12-5-9-14(17-2)10-6-12;/h3-10H,1-2H3;1H/q+1;/p-1
(3)InChIKey: YDSNSDXMWRVLLI-REWHXWOFAN