Detail of "19287-45-7"
- MSDS Download

- CAS Number:
- 19287-45-7
- Name:
Diborane(6)
- Superlist Name:
- Diborane
- Molecular Structure:

- Formula:
- B2H6
- Molecular Weight:
- 27.68
- Synonyms:
- Borane(B2H6); Boron hydride (B2H6); Diborane; Diborane (B2H6); Diboron hexahydride;Hydrogen boride (H6B2)
- EINECS:
- 242-940-6
- Density:
- 0.477
- Melting Point:
- -165 ºC
- Boiling Point:
- -93 ºC
- Flash Point:
- -90 ºC
- Solubility:
- Decomposes
- Hazard Symbols:


- Risk Codes:
- R12;R23/24/25;R36/37/38
- Safety:
- Poison by inhalation. An irritant to skin, eyes, and mucous membranes comparable to chlorine, fluorine, arsine, and phosgene. The liquid causes local inflammation, blisters, redness, and swelling. Injuries to central nervous system, liver, and kidneys have also been produced in experimental animals. Similar observations have been reported in humans, resulting at times in a reaction resembling metal fume fever. Human exposure to pentaborane has produced signs of severe central nervous system irritation such as drowsiness, dizziness, visual disturbances, muscle twitching, and in severe cases, painful muscle spasm. Dangerously flammable when exposed to heat or flame or by chemical reaction. On contact with moisture, hydrogen is usually evolved. Highly explosive when exposed to heat or flame. Explosive reaction with air, tetravinyllead, O2 above 165°C, octanol oxime + sodium hydroxide, benzene vapor, HNO3Cl2. Violent reaction with halocarbon liquids. Other boron hydrides evolve H2 upon contact with moisture or can propagate a flame rapidly enough to cause an explosion. Heat can cause these materials to decompose violently or at least to evolve H2. They also react with water or steam to evolve hydrogen. Reaction with Al or Li forms complex hydrides that may ignite spontaneously in air. Powerful oxidizing agents, such as chlorine gas, etc., can react violently with boron hydrides. Pentaborane (stable) is spontaneously flammable in air. See also BORANES and HYDRIDES.
Analytical Methods:
For occupational chemical analysis use NIOSH: Diborane, 6006. Details
- Transport Information:
- UN 1911/1953
Famous Chemical Enterprises
-
Livzon
-
Total
-
Shell
-
Dupont
-
Exxonmobil
-
Akzonobel
-
Basf
-
Bayer
-
BP
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Reference
- Chlorine-containing resin
-
Chlorine-containing resin.
Koski, Erkki; Riihinon, Kalevi (Valmet Oy, Finland). Braz. Pedido PI
BR 7508657 8 Sep 1976, 19 pp. (Portuguese). (Brazil). CODEN:
BPXXDX. CLASS: IC: D21F001-48. PRIORITY: FI 74-3792 30 Dec
1974. DOCUMENT TYPE: Patent CA Section: 36 (Plastics
Manufacture and Processing)
The thermal stability and resistance to discoloration of Cl-contg. olefin
polymers was improved by treating the powd. polymer with a gaseous
hydride prior to molding or processing. Thus, 100 g powd. PVC
[9002-86-2], particle size 1-100 .mu., was treated with 900 mL
gaseous diborane (I) [19287-45-7] and stored 3 days under ambient
conditions. The I was removed by flushing with air and the treated PVC
was molded and exposed in an oil bath at 200.degree.. The I-treated
resin turned brown after 40 min compared with 15-25 min for untreated
PVC and PVC contg. a com. Sn stabilizer.
- Reactive microgels
-
Reactive microgels. 7. Microgels containing hydroxyl groups.
Seitz, Ulrich (Inst. Tech. Chem., Univ. Stuttgart, Stuttgart, Ger.).
Makromol. Chem., 178(6), 1689-92 (German) 1977. CODEN:
MACEAK. DOCUMENT TYPE: Journal CA Section: 36 (Plastics
Manufacture and Processing)
The pendant vinyl groups in poly(1,4-divinylbenzene) [25989-95-1] or
tech. poly(divinylbenzene) [9003-69-4] microgels are converted into OH
groups by hydroboration with B2H6 [19287-45-7]. B2H6 penetrates
the microgel network rapidly and reacts with all vinyl groups.
-
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Diborane(6)



Analytical Methods:
For occupational chemical analysis use NIOSH: Diborane, 6006. Details
Famous Chemical Enterprises
-
Livzon -
Total -
Shell -
Dupont -
Exxonmobil -
Akzonobel -
Basf -
Bayer -
BP
Please post your buying leads,so that our qualified suppliers
will soon contact you!
*Required Fields
Reference
- Chlorine-containing resin
- Chlorine-containing resin. Koski, Erkki; Riihinon, Kalevi (Valmet Oy, Finland). Braz. Pedido PI BR 7508657 8 Sep 1976, 19 pp. (Portuguese). (Brazil). CODEN: BPXXDX. CLASS: IC: D21F001-48. PRIORITY: FI 74-3792 30 Dec 1974. DOCUMENT TYPE: Patent CA Section: 36 (Plastics Manufacture and Processing) The thermal stability and resistance to discoloration of Cl-contg. olefin polymers was improved by treating the powd. polymer with a gaseous hydride prior to molding or processing. Thus, 100 g powd. PVC [9002-86-2], particle size 1-100 .mu., was treated with 900 mL gaseous diborane (I) [19287-45-7] and stored 3 days under ambient conditions. The I was removed by flushing with air and the treated PVC was molded and exposed in an oil bath at 200.degree.. The I-treated resin turned brown after 40 min compared with 15-25 min for untreated PVC and PVC contg. a com. Sn stabilizer.
- Reactive microgels
- Reactive microgels. 7. Microgels containing hydroxyl groups. Seitz, Ulrich (Inst. Tech. Chem., Univ. Stuttgart, Stuttgart, Ger.). Makromol. Chem., 178(6), 1689-92 (German) 1977. CODEN: MACEAK. DOCUMENT TYPE: Journal CA Section: 36 (Plastics Manufacture and Processing) The pendant vinyl groups in poly(1,4-divinylbenzene) [25989-95-1] or tech. poly(divinylbenzene) [9003-69-4] microgels are converted into OH groups by hydroboration with B2H6 [19287-45-7]. B2H6 penetrates the microgel network rapidly and reacts with all vinyl groups.
Please post your buying leads
so that our qualified suppliers will soon contact you!
so that our qualified suppliers will soon contact you!
©2008 LookChem.com,License:ICP NO.:Zhejiang10014259
[Hangzhou]86-571-85317600,85317603,85317620

