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CAS No.: | 2016-57-1 |
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Name: | Decylamine |
Article Data: | 71 |
Molecular Structure: | |
Formula: | C10H23N |
Molecular Weight: | 157.299 |
Synonyms: | Decylamine(6CI,8CI);1-Aminodecane;Decanamine;Kemamine P 190D;Monodecylamine;n-Decylamine; |
EINECS: | 217-957-7 |
Density: | 0.797 g/cm3 |
Melting Point: | 12-14 °C(lit.) |
Boiling Point: | 221.403 °C at 760 mmHg |
Flash Point: | 85.556 °C |
Appearance: | colourless liquid |
Hazard Symbols: | T |
Risk Codes: | 20/22-24-34 |
Safety: | 26-36/37/39-45 |
Transport Information: | UN 2922 8/PG 3 |
PSA: | 26.02000 |
LogP: | 3.78610 |
1-aminodecane
Conditions | Yield |
---|---|
With palladium 10% on activated carbon; hydrogen In methanol at 100℃; under 37503.8 Torr; Reagent/catalyst; Flow reactor; | 100% |
Conditions | Yield |
---|---|
With sodium tetrahydroborate In water at 100℃; for 8h; pH=5.5; | 97% |
With hydrogen; acetic acid at 20℃; under 6080.41 Torr; for 6h; Catalytic behavior; Temperature; Pressure; Sealed tube; chemoselective reaction; | 90% |
With ammonia; hydrogen In water; isopropyl alcohol at 80℃; under 15001.5 Torr; for 24h; Autoclave; | 88% |
Conditions | Yield |
---|---|
With hydrogen at 100℃; under 7500.75 Torr; for 12h; Sealed tube; Autoclave; | 97% |
1-azidodecane
1-aminodecane
Conditions | Yield |
---|---|
With magnesium In methanol for 0.25h; | 95% |
With hydrogenchloride; indium In tetrahydrofuran at 20℃; for 2h; | 92% |
With tin(ll) chloride; aluminium trichloride In methanol for 1h; Ambient temperature; | 88% |
decyl-N,N-diallylamine
1-aminodecane
Conditions | Yield |
---|---|
With Wilkinson's catalyst In water; acetonitrile for 2h; Heating; | 90% |
Conditions | Yield |
---|---|
With hydrogenchloride; sodium hydroxide In tetrahydrofuran; water NaN3 was added to a THF soln. of trialkylborane followed by 10% aq. HCl, mixt. was gently relfuxed overnight; dild. with aq. HCl, extd. with ether, aq. layer was made basic (aq. NaOH) and ext. with ether, ether exts. were dried over KOH, filtered, evapd.; | 80% |
Conditions | Yield |
---|---|
With sodium tetrahydroborate; titanium tetrachloride In 1,2-dimethoxyethane for 14h; Ambient temperature; | 75% |
With sodium (tert-butylamino)trihydroborate In tetrahydrofuran at 66℃; for 120h; further reducing agent: sodium (dimethylamino)trihydroborat (NaDMAB); | 46% |
With copper oxide-chromium oxide; ammonia at 350℃; under 294203 Torr; Hydrogenation; | |
With ethandithiol; sodium tetrahydroborate | |
With 1,10-Phenanthroline; diethoxymethylane; iron(II) acetate In toluene at 100℃; for 28h; Inert atmosphere; chemoselective reaction; | 49 %Chromat. |
1-aminodecane
Conditions | Yield |
---|---|
With ammonium hydroxide; sodium hypochlorite In water 1.) 0 deg C, 5-10 min, 2.) 0 deg C -> room temperature; | 74% |
methanol
N-decyl-N-ethylpropanamide
A
1-aminodecane
B
acetic acid methyl ester
Conditions | Yield |
---|---|
Stage #1: N-decyl-N-ethylpropanamide With triphenyl phosphite; chlorine; triethylamine In dichloromethane at -30℃; Stage #2: methanol In dichloromethane at -30 - 20℃; Stage #3: With water | A 72% B n/a |
Conditions | Yield |
---|---|
With [2,2]bipyridinyl; C24H26FeN6(2+)*2ClO4(1-); bis-[(trifluoroacetoxy)iodo]benzene In acetonitrile at 80℃; for 2h; Catalytic behavior; Reagent/catalyst; Glovebox; Inert atmosphere; Molecular sieve; chemoselective reaction; | A 5% B 66% |
MF: C10H23N
MW: 157.3
EINECS: 217-957-7
Mol File: 2016-57-1.mol
mp: 12-14 °C(lit.)
bp: 216-218 °C(lit.)
density: 0.787 g/mL at 25 °C(lit.)
refractive index: n20/D 1.436(lit.)
Fp: 186 °F
CAS DataBase Reference: 2016-57-1(CAS DataBase Reference)
NIST Chemistry Reference: 2016-57-1(NIST)
The structure of Decylamine is:
1. | skn-rbt 100 µg/24H open | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. | ||
2. | orl-rat LD50:280 mg/kg | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. | ||
3. | skn-rbt LD50:350 mg/kg | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. | ||
4. | ipr-mus LD50:71 mg/kg | EJMCA5 European Journal of Medicinal Chemistry. Chimie Therapeutique. 26 (1991),517. |