Detail of "20249-05-2"
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- Aqueous suspensions of azo compounds
- Aqueous suspensions of azo compounds. Ruzicka, Karel; Sulakova, Eva (Czech. ).Several substances are used for example 28005-74-5 which is its cas registry number. Czech. CS 215389 B 29 Feb 1984,4 pp. (Czech). (Czechoslovakia). CODEN: CZXXA9. CLASS: IC: C09B067-46. ICA: C09B029-00. APPLICATION: CS 80-6351 29 Sep 1980. DOCUMENT TYPE: Patent CA Section: 41 (Dyes, Organic Pigments, Fluorescent Brighteners, and Photographic Sensitizers) Aq. suspensions of azo dyes are prepd. by coupling a diazotized heterocyclic or arom. amine with an aq. emulsion of a coupling component above its m.p. and in the presence of surfactants. The coupling in aq. emulsion improves the temp. control and selectivity of the reaction. Thus, 2-MeC6H4N(CH2CH2OH)2 [28005-74-5] was dispersed at 50° in H2O contg. 5% oxyethylated tall oil and coupled with an aq. soln. of 4-O2NC6H4N2Cl at 35-40° within ~5 min. Similarly prepd. were azo dyes from 2,5-(HO3S)2C6H3NH2 [98-44-2] 2,5-Me(MeO)C6H3NH2 [50868-72-9], 2,4-Cl(O2N)C6H3NH2 [121-87-9] and PhN(Et)CH2CH2CN [148-87-8], and 2,4,6-Br(O2N)2C6H2NH2 [1817-73-8] and 2,5-EtO(AcNH)C6H3N(CH2CH2OAc)2 [20249-05-2]. .


