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| CAS No.: | 206-44-0 |
|---|---|
| Name: | Fluoranthene |
| Article Data: | 113 |
| Molecular Structure: | |
|
|
|
| Formula: | C16H10 |
| Molecular Weight: | 202.255 |
| Synonyms: | 1,2-(1,8-Naphthylene)benzene;Benzene, 1,2-(1,8-naphthalenediyl)-;Benzo[jk]fluorene;ClusterCarbon;Idryl;NSC 6803; |
| EINECS: | 205-912-4 |
| Density: | 1.249 g/cm3 |
| Melting Point: | 109 °C |
| Boiling Point: | 374.998 °C at 760 mmHg |
| Flash Point: | 168.375 °C |
| Solubility: | insoluble in water |
| Appearance: | Light yellow fine crystals |
| Hazard Symbols: |
 Xn,  N,  F,  T
|
| Risk Codes: | 22-36/37/38-40-67-65-50/53-38-11-39/23/24/25-23/24/25 |
| Safety: | 37/39-26-36/37-24/25-23-62-61-60-45-16-7 |
| Transport Information: | UN 1593 6.1/PG 3 |
| PSA: | 0.00000 |
| LogP: | 4.48720 |
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- 206-44-0
fluoranthene
| Conditions | Yield |
|---|---|
| With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); 1-Adamantanecarboxylic acid In N,N-dimethyl acetamide at 110℃; for 24h; Inert atmosphere; | 98% |
- 1246661-49-3
1-(2-fluorophenyl)naphthalene
- 206-44-0
fluoranthene
| Conditions | Yield |
|---|---|
| With dimethyldimesitylsilane In chlorobenzene at 110℃; for 8h; Friedel Crafts reaction; Inert atmosphere; | 93% |
| With aluminum oxide at 150℃; for 60h; Inert atmosphere; | 79% |
- 141362-13-2
1-(2-trifluormethanesulfonyloxyphenyl)naphthalene
- 206-44-0
fluoranthene
| Conditions | Yield |
|---|---|
| With 1,8-diazabicyclo[5.4.0]undec-7-ene; triphenylphosphine; lithium chloride; bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 140℃; for 6h; | 90% |
| With 1,8-diazabicyclo[5.4.0]undec-7-ene; triphenylphosphine; lithium chloride; bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 140℃; for 6h; other aryl bromides; other MOM phenyl ethers; | 90% |
- 1598372-53-2
6b,7,10,10a-tetrahydrofluoranthene-6b,10a-diol
- 206-44-0
fluoranthene
| Conditions | Yield |
|---|---|
| With toluene-4-sulfonic acid In toluene at 75℃; for 6.5h; | 90% |
| Conditions | Yield |
|---|---|
| With tris(dibenzylideneacetone)dipalladium (0); 1,8-diazabicyclo[5.4.0]undec-7-ene; tricyclohexylphosphine In N,N-dimethyl-formamide at 155℃; for 48h; Suzuki coupling, Heck coupling; | 87% |
| Conditions | Yield |
|---|---|
| With tris(dibenzylideneacetone)dipalladium (0); 1,8-diazabicyclo[5.4.0]undec-7-ene; tricyclohexylphosphine In N,N-dimethyl-formamide at 155℃; for 48h; Suzuki coupling, Heck coupling; | 87% |
- 198780-91-5
3,9-Diethynyl-phenanthrene
A
- 206-44-0
fluoranthene
B
- 27208-37-3
cyclopenta[c,d]pyrene
C
- 201-06-9
acephenanthrylene
| Conditions | Yield |
|---|---|
| at 1000℃; under 0.01 Torr; Mechanism; var. of temp.; other polyclic aromatic hydrocarbon with ethynyl subst.; | A 2% B 1% C 4% D 8% E 85% |
| Conditions | Yield |
|---|---|
| at 1000℃; under 0.01 Torr; Further byproducts given; | A 2% B 1% C 8% D 85% |
- 607731-70-4
1-phenyl-2-iodonaphthalene
- 206-44-0
fluoranthene
| Conditions | Yield |
|---|---|
| With palladium diacetate; cesium pivalate; bis-diphenylphosphinomethane In N,N-dimethyl-formamide at 110℃; for 24h; | 81% |
| With palladium diacetate; potassium pivalate; DavePhos In N,N-dimethyl-formamide at 100℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube; | 70% |
| With palladium diacetate; cesium pivalate; bis-diphenylphosphinomethane In N,N-dimethyl-formamide at 110℃; for 12h; Inert atmosphere; |
- 1071935-91-5
2-(2-bromo-acenaphthylen-yl)-3,6-dihydro-2H-pyran
- 206-44-0
fluoranthene
| Conditions | Yield |
|---|---|
| With tetrabutyl-ammonium chloride; palladium diacetate; caesium carbonate; triphenylphosphine In N,N-dimethyl-formamide at 85 - 90℃; for 1.5h; Inert atmosphere; | 80% |
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Consensus Reports
IARC Cancer Review: Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal No Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 32 (1983),p. 355.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.
Analytical Methods
For occupational chemical analysis use NIOSH: Polynuclear Aromatic Hydrocarbons (HPLC), 5506; (GC), 5515.
Specification
1. Introduction of Fluoranthene
Fluoranthene, with the CAS No. 206-44-0, has the IUPAC Name of Pentyl nitrite, and it is one kind of light yellow fine crystals. This chemical is insoluble in water, and it belongs to the Product Categories which include Color Former & Related Compounds ; Functional Materials; Sensitizer ; E-LAlphabetic; FA - FLEnvironmental Standards; Alpha Sort; F; PAHs; Volatiles/ Semivolatiles. Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as Fluoranthene, and strong oxidizing agents. They can react exothermically with bases and with diazo compounds.
2. Properties of Fluoranthene
Fluoranthene has the following properties: (1)Melting Point: 109 °C; (2)Flash Point: 8.9 °C; (3)Boiling Point: 105.1 °C at 760 mmHg; (4)Vapour Pressure: 34.9 mmHg at 25°C; (5)Enthalpy of Vaporization: 32.98 kJ/mol; (6)Refractive Index: 1.0996.
3. Structure Descriptors of Fluoranthene
(1). InChI: InChI=1S/C16H10/c1-2-8-13-12(7-1)14-9-3-5-11-6-4-10-15(13)16(11)14/h1-10H
(2). InChIKey: InChIKey=GVEPBJHOBDJJJI-UHFFFAOYSA-N
(3). Smiles: c12c3c4ccccc4c1cccc2ccc3
4. Toxicity of Fluoranthene
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intravenous | 100mg/kg (100mg/kg) | U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00205, | |
| rabbit | LD50 | skin | 3180mg/kg (3180mg/kg) | American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. | |
| rat | LD50 | oral | 2gm/kg (2000mg/kg) | American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. |
5. Safety Information of Fluoranthene
Poison by intravenous route. Moderately toxic by ingestion and skin contact. Questionable carcinogen with experimental tumorigenic data. Human mutation data reported. Combustible when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes:
Xn;
N;
F;
T Risk Statements:
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
R40:Limited evidence of a carcinogenic effect.
R67:Vapours may cause drowsiness and dizziness.
R65:Harmful: may cause lung damage if swallowed.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R38:Irritating to skin.
R11:Highly flammable.
R39/23/24/25:Danger of very serious irreversible effects and toxic by inhalation, in contact with skin and if swallowed.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements:
S37/39:Wear suitable gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37:Wear suitable protective clothing and gloves.
S24/25:Avoid contact with skin and eyes.
S23:Do not breathe vapour.
S62:If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S60:This material and its container must be disposed of as hazardous waste.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S16:Keep away from sources of ignition.
S7:Keep container tightly closed.
RIDADR: UN 1593 6.1/PG 3
WGK Germany: 2
RTECS: LL4025000
6. Use of Fluoranthene
Fluoranthene can be used as constituent of coal tar & petroleum derived asphalt used as lining material to protect interior of steel & ductile-iron potable water pipes and storage tanks.
7. Production of Fluoranthene
Raw Materials are Coal Tar-->Asphaltum-->Anthracene Oil-->Light Solvent Naphtha.