Detail of > 21149-17-7
- CAS Number:
- 21149-17-7
- Name:
2-Propenoic acid,2-[[(phenylmethoxy)carbonyl]amino]-, methyl ester
- Superlist Name:
- Methyl 2-{[(benzyloxy)carbonyl]amino}acrylate
- Formula:
- C12H13NO4
- Molecular Structure:
![Molecular Structure of 21149-17-7 (2-Propenoic acid,2-[[(phenylmethoxy)carbonyl]amino]-, methyl ester)](http://www.lookchem.com/300w/2010/0620/21149-17-7.jpg)
- Synonyms:
- Acrylicacid, 2-(carboxyamino)-, 2-benzyl methyl ester (6CI,8CI);N-Benzyloxycarbonyldehydroalanine methylester;
- Molecular Weight:
- 235.24
- Density:
- 1.182 g/cm3
- Boiling Point:
- 358 °C at 760 mmHg
- Flash Point:
- 170.3 °C
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Reference
- A short synthetic approach to chiral serine azido derivatives
- Several substances are used for example 21149-17-7 which is its cas registry number. A short synthetic approach to chiral serine azido derivatives. Panda, Gautam; Rao, N. Venugopal (Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, ON K1A 0R6, Can.). Synlett, (4), 714-716 (English) 2004 Georg Thieme Verlag. CODEN: SYNLES. ISSN: 0936-5214. DOCUMENT TYPE: Journal CA Section: 34 (Amino Acids, Peptides, and Proteins) Section cross-reference(s): 23 The authors report a new synthetic methodol. for the synthesis of chiral (S)-serine azido derivs., RNHCH(CH2N3)COY (R = Boc, Cbz; Y = OH, H, Me; R = Fmoc, Y = OH), from Mitsunobu nucleophilic addn. 21149-17-7 is also in the experiment. to N-protected (S)-serine Weinreb amides, RNHCH(CH2OH)CON(OMe)Me. In this way, acidity of the a-proton of the serine is reduced and it allows nucleophilic addn. reaction onto Weinreb amide to furnish chiral azide-contg. serine derivs. ..
- A short synthetic approach to chiral serine azido derivatives
- Several substances are used for example 21149-17-7 which is its cas registry number. A short synthetic approach to chiral serine azido derivatives. Panda, Gautam; Rao, N. Venugopal (Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, ON K1A 0R6, Can.). Synlett, (4), 714-716 (English) 2004 Georg Thieme Verlag. CODEN: SYNLES. ISSN: 0936-5214. DOCUMENT TYPE: Journal CA Section: 34 (Amino Acids, Peptides, and Proteins) Section cross-reference(s): 23 The authors report a new synthetic methodol. for the synthesis of chiral (S)-serine azido derivs., RNHCH(CH2N3)COY (R = Boc, Cbz; Y = OH, H, Me; R = Fmoc, Y = OH), from Mitsunobu nucleophilic addn. 21149-17-7 is also in the experiment. to N-protected (S)-serine Weinreb amides, RNHCH(CH2OH)CON(OMe)Me. In this way, acidity of the a-proton of the serine is reduced and it allows nucleophilic addn. reaction onto Weinreb amide to furnish chiral azide-contg. serine derivs. ..
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