Detail of > 21286-54-4
- CAS Number:
- 21286-54-4
- Name:
Bicyclo[2.2.1]heptane-1-methanesulfonylchloride, 7,7-dimethyl-2-oxo-, (1S,4R)-
- Superlist Name:
- D(+)-10-Camphorsulfonyl chloride
- Formula:
- C10H15ClO3S
- Molecular Structure:
![Molecular Structure of 21286-54-4 (Bicyclo[2.2.1]heptane-1-methanesulfonylchloride, 7,7-dimethyl-2-oxo-, (1S,4R)-)](http://www.lookchem.com/300w/2010/0620/21286-54-4.jpg)
- Synonyms:
- 10-Bornanesulfonylchloride, 2-oxo-, (+)- (8CI);10-Camphorsulfonyl chloride (6CI);Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-, (1S)-;(+)-10-Camphorsulfonic acid chloride;(+)-10-Camphorsulfonyl chloride;(+)-Camphorsulfonyl chloride;(1S)-(+)-10-Camphorsulfonyl chloride;(1S)-(+)-Camphorsulfonyl chloride;(1S)-1-[(Chlorosulfonyl)methyl]-7,7-dimethylbicyclo[2.2.1]heptan-2-one;(1S)-10-Camphorsulfonyl chloride;(1S)-Camphor-10-sulfonyl chloride;(S)-(+)-10-Camphorsulfonyl chloride;(S)-(+)-Camphorsulfonyl chloride;(S)-Camphor-10-sulfonyl chloride;d-10-Camphorsulfonyl chloride;d-Camphorsulfonyl chloride;
- Molecular Weight:
- 250.74
- EINECS:
- 244-314-8
- Density:
- 1.331 g/cm3
- Melting Point:
- 67-68 °C
- Boiling Point:
- 349.4 °C at 760 mmHg
- Flash Point:
- 165.1 °C
- Appearance:
- white to light yellow crystal powder
- Hazard Symbols:
C- Risk Codes:
- 34
- Safety:
- 26-36/37/39-45Details
- Transport Information:
- UN 3261 8/PG 2
Related products
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Reference
- Synthesis of (+)-(2R,8aS)-10-(camphorylsulfonyl)oxaziridine
- Synthesis of (+)-(2R,8aS)-10-(camphorylsulfonyl)oxaziridine. Towson, James C.; Weismiller, Michael C.; Lal, G. Sankar; Sheppard, Aurelia C.; Davis, Franklin A. (Dep. Chem., Drexel Univ., Philadelphia, PA 19104, USA). Org. Synth., 69, 158-68 (English) 1990. CODEN: ORSYAT. ISSN: 0078-6209. DOCUMENT TYPE: Journal CA Section: 30 (Terpenes and Terpenoids) Amidation of (+)-10-camphosulfonyl chloride by NH4OH in CH2Cl2 gave 90% (+)-(1S)-1-camphorsulfonamide which underwent Amberlyst 15 catalyzed cyclocondensation in PhMe to give 90-95% imine I. 60886-80-8 and 21286-54-4 which are cas registry numbers of substances are two of reagents here. The last was treated with aq. oxone and K2CO3 to give 84% title compd. II. .
- Herbicide, synthesis of 2,3-dihydro-3,3-dimethyl-2-ethoxybenzofuran-5-yl methanesulfonate
- Herbicide, synthesis of 2,3-dihydro-3,3-dimethyl-2-ethoxybenzofuran-5-yl methanesulfonate. Anon. (Engl.Chemicals with cas numbers 62424-63-9 and 21286-54-4 also play role.). Res. Discl., 152, 27 (English) 1976. CODEN: RSDSBB. DOCUMENT TYPE: Journal CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) Section cross-reference(s): 5 Racemic and optical isomers of I, useful as herbicides, were prepd. via esterification of II with MeSO2Cl; II were resolved via esterification with (+)-10-camphorsulfonyl chloride. .
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