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CAS No.: | 2134-29-4 |
---|---|
Name: | 3-hydroxypropionaldehyde |
Article Data: | 91 |
Molecular Structure: | |
Formula: | C3H6 O2 |
Molecular Weight: | 74.0794 |
Synonyms: | Hydracrylaldehyde(6CI,7CI,8CI);3-Hydroxypropanal;3-Hydroxypropionaldehyde;3-Oxo-1-propanol;Hydracrolein;Reuterin;b-Hydroxypropanal;b-Hydroxypropionaldehyde; |
EINECS: | 218-365-1 |
Density: | 1.016g/cm3 |
Boiling Point: | 168.2°Cat760mmHg |
Flash Point: | 61.8°C |
Solubility: | Toxicity data (The meaning of any toxicologica"> high (calculated)
Stability
Toxicology
Toxicity data |
PSA: | 37.30000 |
LogP: | -0.43230 |
Conditions | Yield |
---|---|
With C14H14N2O4(2+)*2BF4(1-) In water at 45℃; under 1275.13 Torr; for 0.2h; Pressure; Reagent/catalyst; Temperature; | 94.8% |
With water In water-d2 at 20℃; for 336h; | 50% |
With sulfuric acid |
Conditions | Yield |
---|---|
With acetic acid; bromamine B In water at 29.9℃; Kinetics; Thermodynamic data; Mechanism; ΔH(excit.), ΔS(excit.), ΔG(excit.); variation of substrate and reagents concentration; solvent isotope effect; | 76% |
With acetic acid; bromamine B In water at 29.9℃; | 76% |
With pyridinium chlorochromate In dimethyl sulfoxide for 6h; Kinetics; Mechanism; Thermodynamic data; Εa, log A, ΔS(excit.), ΔG(excit.); |
Conditions | Yield |
---|---|
With dihydrogen peroxide In acetonitrile at 70℃; Reagent/catalyst; | A 6.8% B 74.7% C 10.4% |
With manganese(IV) oxide; dihydrogen peroxide In acetonitrile at 70℃; Reagent/catalyst; | A 2.5% B 5.6% C 1.8% |
With manganese(IV) oxide; dihydrogen peroxide In acetonitrile at 70℃; Reagent/catalyst; | A 2.8% B 0.1% C 3.1% |
With dihydrogen peroxide In acetonitrile at 70℃; Reagent/catalyst; | A 3% B 3.4% C 3.5% |
Conditions | Yield |
---|---|
perchloric acid In water; acetic acid at 29.9℃; Rate constant; Mechanism; Thermodynamic data; Rate constants also at 308, 313 and 318 K, at different acidities and at different proportions of NBA; ΔH(excit.), ΔS(excit.), ΔG(excit.); | 71% |
Conditions | Yield |
---|---|
In water at 400℃; | A 60% B 10% C 30% |
Conditions | Yield |
---|---|
With Lactobacillus reuteri SD 2112 In water at 37℃; for 2.5h; | 45% |
entsteht als Zwischenprodukt bei der Bildung von Acrolein durch Einw. des Bacillus amaracrylus; | |
With Lactobacillus coryniformis 394 In water at 25℃; | |
With Klebsiella pneumoniae CGMCC 1.9131 In aq. buffer at 37℃; pH=6.8; Microbiological reaction; |
glycerol
A
methanol
B
propan-1-ol
C
propylene glycol
D
propane
E
3-Hydroxypropanal
F
carbon dioxide
G
carbon monoxide
H
ethylene glycol
I
propionaldehyde
J
hydroxy-2-propanone
K
isopropyl alcohol
L
acetone
M
acrolein
N
trimethyleneglycol
Conditions | Yield |
---|---|
With hydrogen at 260℃; Catalytic behavior; Temperature; Reagent/catalyst; | A n/a B 28% C 18% D n/a E n/a F n/a G n/a H n/a I n/a J n/a K 15% L n/a M n/a N 14% |
Conditions | Yield |
---|---|
With dihydrogen peroxide In acetonitrile at 70℃; Reagent/catalyst; | A 3.7% B 12.9% |
3,3-diethoxypropan-1-ol
3-Hydroxypropanal
Conditions | Yield |
---|---|
With sulfuric acid; acetone | |
With ozone | |
With hydrogenchloride In water at 60℃; |
Conditions | Yield |
---|---|
With water; potassium carbonate at 12 - 18℃; |