Detail of "2142-70-3"

Reference

Ru(II) complexes of cyclohexanediamine and monodentate phosphorus ligands for asymmetric ketone hydrogenation

All Rights Reserved. Ru(II) complexes of cyclohexanediamine and monodentate phosphorus ligands for asymmetric ketone hydrogenation. Xu, Yingjian; Docherty, Gordon F.; Woodward, Gary; Wills, Martin ( Asymmetric Catalysis Group, Department of Chemistry, Warwick University, Coventry CV4 7AL, UK). Tetrahedron: Asymmetry, 17(20), 2925-2929 (English) 2006 Elsevier Ltd. CODEN: TASYE3. ISSN: 0957-4166. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) The incorporation of a trans-1,2-diaminocyclohexane in place of DPEN provides improvements in enantioselectivity to asym. ketone hydrogenation reactions using BrXuPHOS-Ru-diamine catalysts.There are some commonly used reagents with their cas registry numbers 114446-55-8 and 2142-70-3 in this article. Substrates contg. halogenated aryl rings are particularly compatible with this catalyst, however, a-chlorinated ketones remain resistant to redn. under any conditions. .