CAS No.2144-53-8,2-(Perfluorohexyl)ethyl methacrylate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	2144-53-8
Name:	2-(Perfluorohexyl)ethyl methacrylate
Article Data:	9

Formula:	C₁₂H₉F₁₃O₂
Molecular Weight:	432.181
Synonyms:	Methacrylicacid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl ester (7CI,8CI);1-Octanol,3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-, methacrylate (8CI);(Perfluorohexyl)ethyl methacrylate;1H,1H,2H,2H-Perfluorooctyl methacrylate;2-(Perfluorohexyl)ethyl methacrylate;3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-yl 2-methyl-2-propenoate;3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl methacrylate;FAMAC 6;M 1620;
EINECS:	218-407-9
Density:	1.459g/cm³
Boiling Point:	220 °C at 760 mmHg
Flash Point:	84.6 °C
Solubility:	42μg/L at 20℃
Hazard Symbols:
Risk Codes:	36/37/38
Safety:	26-36
PSA:	26.30000
LogP:	5.23460

Synthetic route

: 79-41-4
poly(methacrylic acid)

: 647-42-7
1H,1H,2H,2H-tridecafluoro-n-octanol

: 2144-53-8
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-methylpropenoate

Conditions

Conditions	Yield
With hydroquinone; toluene-4-sulfonic acid In toluene at 115℃; for 5h;	94%
With sulfuric acid; hydroquinone In benzene Heating;
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃;

: 760-93-0
methacryloyl anhydride

: 647-42-7
1H,1H,2H,2H-tridecafluoro-n-octanol

: 2144-53-8
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-methylpropenoate

Conditions

Conditions	Yield
With dmap; triethylamine In dichloromethane; 1,1,2-Trichloro-1,2,2-trifluoroethane at 30℃; for 18h;	76%

: 2043-57-4
1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane

: 5536-61-8
sodium methacrylate

: 2144-53-8
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-methylpropenoate

Conditions

Conditions	Yield
With tetra-n-butylphosphonium chloride In o-xylene; water at 100℃; for 12h; Reagent/catalyst;	71.8%

: 75-25-2
Bromoform

: 647-42-7
1H,1H,2H,2H-tridecafluoro-n-octanol

: 67-64-1
acetone

: 2144-53-8
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-methylpropenoate

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In benzonitrile; acetonitrile at 20℃; for 5h;	70%

...Expand

: 67-66-3
chloroform

: 647-42-7
1H,1H,2H,2H-tridecafluoro-n-octanol

: 67-64-1
acetone

: 2144-53-8
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-methylpropenoate

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In benzonitrile; acetonitrile at 50℃; for 42h;	8.8%

...Expand

: 647-42-7
1H,1H,2H,2H-tridecafluoro-n-octanol

: 920-46-7
Methacryloyl chloride

: 2144-53-8
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-methylpropenoate

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran Yield given;

: 2043-57-4
1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane

: 6900-35-2
potassium methacrylate

A: 647-42-7
1H,1H,2H,2H-tridecafluoro-n-octanol

B: 25291-17-2
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene

C: 2144-53-8
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-methylpropenoate

Conditions

Conditions	Yield
With 10H-phenothiazine In tert-butyl alcohol at 130 - 170℃; for 6 - 9h;

...Expand

: 2043-57-4
1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane

: 6900-35-2
potassium methacrylate

A: 25291-17-2
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene

B: 2144-53-8
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-methylpropenoate

Conditions

Conditions	Yield
With 10H-phenothiazine In tert-butyl alcohol at 160℃; for 9h;

...Expand

: 1H,1H,2H,2H-tridecafluorooctyl 2-chloro-2-methylpropanoate

: 2144-53-8
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-methylpropenoate

Conditions

Conditions	Yield
at 540℃; for 0.55h; Inert atmosphere;	1.36 g

: 31001-77-1
mercaptopropylmethyldimethoxysilane

: 2144-53-8
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-methylpropenoate

: Dimethoxy-methyl-[3-(2-pentafluorophenyl-ethylsulfanyl)-propyl]-silane

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In acetonitrile at 80℃; for 4h;	60%

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Specification

The 2-(Perfluorohexyl)ethyl methacrylate with its cas register number is 2144-53-8. It also can be called as 1,1,2,2-Tetrahydroperfluorooctyl methacrylate and the IUPAC Name about this chemical is 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-methylprop-2-enoate. It belongs to the following product categories, such as monomer, Acrylic Monomers, Fluorinated Acrylics, Monomers and so on.

Physical properties about 2-(Perfluorohexyl)ethyl methacrylate are: (1)ACD/LogP: 6.71; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 6.71; (4)ACD/LogD (pH 7.4): 6.71; (5)ACD/BCF (pH 5.5): 74149.32; (6)ACD/BCF (pH 7.4): 74149.32; (7)ACD/KOC (pH 5.5): 106562.2; (8)ACD/KOC (pH 7.4): 106562.2; (9)#H bond acceptors: 2; (10)#Freely Rotating Bonds: 9; (11)Polar Surface Area: 26.3Å²; (12)Index of Refraction: 1.333; (13)Molar Refractivity: 60.9 cm³; (14)Molar Volume: 296.1 cm³; (15)Polarizability: 24.14x10^-24cm³; (16)Surface Tension: 18.4 dyne/cm; (17)Enthalpy of Vaporization: 45.64 kJ/mol; (18)Vapour Pressure: 0.116 mmHg at 25°C.

Preparation: this chemical can be prepared by 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctan-1-ol and methacrylic acid-anhydride. This reaction will need reagent DMAP, Et₃N and solvent CH₂Cl₂, 1,1,2-trichloro-1,2,2-trifluoro-ethane . The reaction time is 18 hour(s) with reaction temperature of 30 ℃. The yield is about 76%.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CC(=C)C(=O)OCCC(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
(2)InChI: InChI=1S/C12H9F13O2/c1-5(2)6(26)27-4-3-7(13,14)8(15,16)9(17,18)10(19,20)11(21,22)12(23,24)25/h1,3-4H2,2H3
(3)InChIKey: CDXFIRXEAJABAZ-UHFFFAOYSA-N

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