Detail of "2237-93-6"

CAS Number:
2237-93-6
Name:
Digermoxane,1,1,1,3,3,3-hexamethyl-
Molecular Structure:
Formula:
C6H18 Ge2 O
Molecular Weight:
253.5024
Synonyms:
Bis(trimethylgermanium)oxide (6CI); Digermoxane, hexamethyl- (8CI,9CI); Germane, oxybis[trimethyl-(7CI); Bis(trimethylgermyl) oxide; Hexamethyldigermoxane; NSC 92303
Density:
g/cm³
Boiling Point:
°Cat760mmHg
Flash Point:
°C

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Structural study of trialkylalkoxy- or aryloxygermanes and trialkylgermanyl oxides: Structural study of trialkylalkoxy- or aryloxygermanes and trialkylgermanyl oxides. I. Determination of the atomic polarizations of tetraalkylgermanes and trialkylgermanyl oxides. Mermillod-Blardet, Danielle; Fayet, Jean P.; Mauret, Pierre; Dousse, Gabriel; Richelme, Suzy (Lab.Chemicals with cas numbers 2237-93-6 and 2538-70-7 also play role. Chim. Org. Structur., Univ. Paul Sabatier, Toulouse, Fr.). J. Organomet. Chem., 122(1), 35-9 (French) 1976. CODEN: JORCAI. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) The total mol. polarizations, detd. from dielec. permittivity; electronic polarizations, obtained from refractive index dispersion; at. polarizations; and dipole moments of R4Ge (R = Me, Et, Bu) and of R31GeOGeR31 (R1 = Me, Et, Pr) were detd. .

Formation and characterization of R2Ge:O germanones from germanium heterocycles: Formation and characterization of R2Ge:O germanones from germanium heterocycles. Lavayssiere, H.; Barrau, J.; Dousse, G.; Satge, J.Chemical with cas number 2237-93-6 also plays role.; Bouchaut, M. (Lab.Some commonly used reagents like 2237-93-6 is used in this experiment. Chim. Organominer., Univ. Paul Sabatier, Toulouse, Fr.). J. Organomet. Chem., 154(1), C9-C12 (French) 1978. CODEN: JORCAI. ISSN: 0022-328X. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Section cross-reference(s): 28 The thermolysis of Ge oxetanes and adducts of germanium-dioxolanes, oxazolidines and diazolidines with carbonyl compds. leads to transient dialkylgermanones R2GeO characterized by addn. of alkoxygermanes and oxagermacyclopentanes on the Ge-O bond, and by insertion and ring expansion reaction with ethylene oxide, with formation of germadioxolanes. ..