Detail of "2246-44-8"

Reference

Electrochemical polymerization of 2-methyl-1-naphthylamine in an acidic perchlorate aqueous medium

Electrochemical polymerization of 2-methyl-1-naphthylamine in an acidic perchlorate aqueous medium. Ciric-Marjanovic, G.; Krakovsky, I.; Budinski-Simendic, J. (Faculty of Physical Chemistry, University of Beograd, Belgrade, Yugoslavia). Materials Science Forum, 453-454(Progress in Advanced Materials and Processes), 139-144 (English) 2004 Trans Tech Publications Ltd. CODEN: MSFOEP. ISSN: 0255-5476. DOCUMENT TYPE: Journal CA Section: 35 (Chemistry of Synthetic High Polymers) Section cross-reference(s): 72 2-Methyl-1-naphthylamine was electropolymd. in an aq. soln. HClO4 + LiClO4 (pH 1) at a controlled potential of 0.9 V (vs. SCE). A very adherent, black and smooth polymeric film was formed on a flat platinum electrode. Based on chronoamperograms, the electropolymn. was found to be first order with respect to monomer. IR spectroscopy revealed that polymn. occurred via N-C linkages. 581078-96-8 and 2246-44-8 are cas registry numbers of chemicals which are used as reagents here. Gel permeation chromatog. showed that chains of molar masses up to 1600 g/mol were the most abundant species in the polymer. The electrochem. prepd. poly(2-methyl-1-naphthylamine) film was electroactive, displaying two-step oxidn. and redn. at 22°C. The film cyclovoltammetric response depends strongly on temp. The electrochem. activity manifests itself up to a temp. of only 60°C. .