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Detail of "22679-54-5"

  • CAS Number:
  • 22679-54-5
  • Name:
  • Methanone,[4-(1,1-dimethylethyl)phenyl]phenyl-

  • Molecular Structure:
  • Formula:
  • C17H18O
  • Molecular Weight:
  • 238.32
  • Synonyms:
  • 4-tert-Butylbenzophenone 97%;
  • EINECS:
  • 245-154-1
  • Density:
  • 1.017 g/cm3
  • Melting Point:
  • 38-40 °C
  • Boiling Point:
  • 347.7 °C at 760 mmHg
  • Flash Point:
  • 147.6 °C
  • Hazard Symbols:
  • IrritantXi
  • Safety:
  • 22-24/25 Details

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Reference

Synthetic methods and reactions
Synthetic methods and reactions. 168. Ring tert-butylation of benzophenones and benzaldehyde with tert-butyllithium and thionyl chloride. Olah, George A.; Wu, An Hsiang; Farooq, Omar (Donald P. and Katherine B. Loker Hydrocarbon Res. Inst., Univ. South. California, Los Angeles, CA 90089-1661, USA). Synthesis, (12), 1179-82 (English) 1991. CODEN: SYNTBF. ISSN: 0039-7881.There are some commonly used reagents with their cas registry numbers 100-52-7 and 22679-54-5 in this article. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) One-flask ring tert-butylation of benzophenones and benzaldehyde with tert-butyllithium and thionyl chloride, to give, e.g., BzC6H4CMe3-p, is reported. The scope of the reaction and the suggested mechanism are discussed. .
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