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2269-22-9

Basic Information
CAS No.: 2269-22-9
Name: Aluminium tri-sec-butoxide
Article Data: 8
Molecular Structure:
Molecular Structure of 2269-22-9 (Aluminium tri-sec-butoxide)
Formula: C12H27AlO3
Molecular Weight: 246.326
Synonyms: 2-Butanol,aluminum salt (9CI);Aluminum sec-butoxide (6CI,7CI);sec-Butyl alcohol,aluminum salt (8CI);ASB (salt);ASBD;Aluminum 2-butoxide;Aluminumsec-butanolate;Aluminum sec-butylate;Aluminum tri(sec-butylate);Aluminumtri-sec-butoxide;Aluminum tris(sec-butoxide);Tri-sec-butoxyaluminum;Tris(2-butanolato)aluminum;Tris(2-butoxy)aluminum;Tris(sec-butoxy)aluminum;trisec-butoxyalumane;Aluminum tri-sec-butoxide;
EINECS: 218-871-2
Density: 1.237 g/mL at 25 °C
Boiling Point: 40 °C
Flash Point: 82 °F
Solubility: Decomposes in water
Appearance: viscous colourless or pale yellow liquid
Hazard Symbols: IrritantXi; HarmfulXn
Risk Codes: 40-21/22-10
Safety: 45-43-36/37/39-26-16
Transport Information: UN 1992
PSA: 27.69000
LogP: 3.79740
Synthetic route
589-40-2

sec-butyl formate

555-31-7

aluminum isopropoxide

A

2269-22-9

aluminum tri-sec-butoxide

B

isopropyl formate

isopropyl formate

amalgamated aluminium

amalgamated aluminium

2269-22-9

aluminum tri-sec-butoxide

555-31-7

aluminum isopropoxide

sec-butyl formate

sec-butyl formate

2269-22-9

aluminum tri-sec-butoxide

Conditions
ConditionsYield
unter Abdestillieren von Isopropylformiat;
7429-90-5

aluminium

2269-22-9

aluminum tri-sec-butoxide

Conditions
ConditionsYield
In neat (no solvent) treatment of the metal with alcohol in the presence of HgCl2 or I2 as catalysts; identified by elem. anal. for Al and by comparison of the constants withpublished data;
64-18-6

formic acid

2269-22-9

aluminum tri-sec-butoxide

aluminium triformate trihydrate

Conditions
ConditionsYield
In water addn. of water to Al(CH3CHOC2H5)3 (air), formation of hydroxide, addn. of formic acid and water, boiling and evapn., keeping at 60°C till complete evapn., drying (2 d over drierite); TGA, DTA;100%
2269-22-9

aluminum tri-sec-butoxide

123-54-6

acetylacetone

aluminium(III) acetylacetonate

Conditions
ConditionsYield
In ethanol at 0℃;97%
1337458-59-9

1-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)naphthalen-2-ol

2269-22-9

aluminum tri-sec-butoxide

mer-[Al(1-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)naphthalen-2-olate)3]

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Schlenk technique;95%
201230-82-2

carbon monoxide

2269-22-9

aluminum tri-sec-butoxide

939-26-4

2-bromomethylnaphthyl bromide

91759-49-8

Naphthalen-2-yl-acetic acid sec-butyl ester

Conditions
ConditionsYield
1,5-hexadienerhodium(I)-chloride dimer In n-heptane at 75℃; for 14h;91%
123-92-2

3-methyl-1-butyl acetate

2269-22-9

aluminum tri-sec-butoxide

25016-92-6

aluminium triisopentylate

Conditions
ConditionsYield
In neat (no solvent) byproducts: sec-Bu-OAc; N2 atmosphere; exchange reaction (111°C); distn. of butyl ester;90%
2269-22-9

aluminum tri-sec-butoxide

7439-95-4

magnesium

Mg{Al(OCH(CH3)CH2CH3)4}2

Conditions
ConditionsYield
With Hg2Cl2 In butan-1-ol byproducts: H2; under N2; addn. of Mg turnings and Hg2Cl2 to stirred soln. of 2 equiv. of Al(O-sec-Bu)3 in sec-butanol, refluxed (7 d); evapn. (vac.), fractional distn. at 140-165°C/0.03 Torr, elem. anal.;86%
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Specification

The Aluminium tri-sec-butoxide, with the CAS registry number 2269-22-9 and EINECS registry number 218-871-2, has the systematic name of trisec-butoxyalumane. And the molecular formula of this chemical is C12H27AlO3. It is a kind of viscous colourless or pale yellow liquid, and belongs to the following product categories: Organic-metal salt; Al (Alminum) Compounds; Classes of Metal Compounds; Typical Metal Compounds; Aluminum; Micro/Nanoelectronics; Solution Deposition Precursors. What's more, it is used as active catalyst, reducer of aldehydes and ketones, gelling agent of paint and ink, and water repellent substance of woof.

The physical properties of Aluminium tri-sec-butoxide are as following: (1)#H bond acceptors: 3; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 9; (4)Polar Surface Area: 27.69 Å2.

You should be cautious while dealing with this chemical. It is a kind of flammable chemical which is harmful in contact with skin and if swallowed. What's more, there's limited evidence of a carcinogenic effect. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; Keep away from sources of ignition - No smoking; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: CCC(C)O[Al](OC(C)CC)OC(C)CC
(2)InChI: InChI=1/3C4H9O.Al/c3*1-3-4(2)5;/h3*4H,3H2,1-2H3;/q3*-1;+3/rC12H27AlO3/c1-7-10(4)14-13(15-11(5)8-2)16-12(6)9-3/h10-12H,7-9H2,1-6H3
(3)InChIKey: WOZZOSDBXABUFO-DYGDCWSTAN