Detail of "22856-30-0"

Reference

Polymeric, electrically conducting m-(p-diisocyanobenzene)-2,3-naphthalocyaninatoiron(II)

Polymeric, electrically conducting m-(p-diisocyanobenzene)-2,3-naphthalocyaninatoiron(II). Deger, S.; Hanack, M. (Inst. Org. Chem., Univ. Tuebingen, Tuebingen D-7400, Fed. Rep. Ger.). Springer Ser. Solid-State Sci., 63(Electron. Prop. Polym. Relat. Compd.), 327-30 (English) 1985. CODEN: SSSSDV. ISSN: 0171-1873. DOCUMENT TYPE: Journal CA Section: 36 (Physical Properties of Synthetic High Polymers) Section cross-reference(s): 76, 78 The refluxing of iron 2,3-naphthalocyanine (I) [26603-19-0] with excess p-diisocyanobenzene (II) gave the title polymer [99936-76-2] which was insol. in org. solvents and had elec. cond. 2 ′ 10-3 and 4 ′ 10-3 S/cm in CHCl3 and Me2CO, resp. The elec. cond. increased to 1 ′ 10-2 S/cm when the polymer was doped with iodine. I was prepd. by addn. of Fe(CO)5 [13463-40-6] to a soln. of 2,3-dicyanonaphthalene [22856-30-0] at bis(p-diisocyanobenzene)iron 2,3-naphthalocyanine which contained oligomers. Treatment of I with excess II in MeOH at room temp. gave impure bis(p-diisocyanobenzene)iron 2,3-naphthalocyanine which contained oligomers and had elec. cond. 3 ′ 10-4 S/cm.