Products Categories
| CAS No.: | 2288-13-3 |
|---|---|
| Name: | METHYLSILATRANE |
| Article Data: | 15 |
| Molecular Structure: | |
|
|
|
| Formula: | C7H15 N O3 Si |
| Molecular Weight: | 189.286 |
| Synonyms: | 1-Methylsilatrane;Methylsilatrane |
| EINECS: | 218-928-1 |
| Density: | 1.12 g/cm3 |
| Melting Point: | 152 °C |
| Boiling Point: | 228.1 °C at 760 mmHg |
| Flash Point: | 91.7 °C |
| Solubility: | Insoluble in water |
| Appearance: | White powder |
| Risk Codes: | 22-36/37/38 |
| Safety: | Moderately toxic by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic vapors of NOx. |
| PSA: | 30.93000 |
| LogP: | -0.12800 |
- 483366-12-7(2S,4R)-1-Boc-2-cyano-4-hydroxypyrrolidine
- 361456-36-2METHYL (R)-(+)-ISOCYANATO-3-PHENYLPROPI&
- 5156-58-1N-(1-Benzyl-4-pipperidinyl)-N-phenylpropanamide HCl
- 81281-59-67-Benzylideneaminotheophylline
- 50288-62-5threo-Phenyl-2-piperidyl acetamide
- 82993-81-5D-threo-Ritalinic acid hydrochloride
- 47087-37-6Z-D-Glu-OMe
- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 240444-70-62,3,5,6-Tetrafluor-4-(methoxymethyl)benzyl-2,2-dimethyl-3-(prop-1-en-1-yl)cyclopropancarboxylat
- 68439-39-4Poly(oxy-1,2-ethanediyl), alpha-(2-ethylhexyl)-omega-hydroxy-,
- 2031-67-6
Methyltriethoxysilan
- 135718-12-6
2,2-dimethyl-6-<2-(trimethylsiloxy)ethyl>-1,3,6,2-dioxazasilocane
- 2288-13-3
1-methylsilatrane
| Conditions | Yield |
|---|---|
| With sodium isopropylate In isopropyl alcohol for 20h; | 85% |
- 2031-67-6
Methyltriethoxysilan
- 144967-53-3
2-Methyl-6-(2-trimethylsilanyloxy-ethyl)-2-vinyl-[1,3,6,2]dioxazasilocane
- 2288-13-3
1-methylsilatrane
| Conditions | Yield |
|---|---|
| With sodium isopropylate In isopropyl alcohol for 20h; | 80% |
- 2031-67-6
Methyltriethoxysilan
- 118162-82-6
2-methyl-2-phenyl-6-(2-hydroxyethyl)-1,3,6,2-dioxazasilocane
- 2288-13-3
1-methylsilatrane
| Conditions | Yield |
|---|---|
| With sodium isopropylate In isopropyl alcohol for 10h; | 78% |
- 144967-54-4
2-methyl-2-phenyl-6-<2-(trimethylsiloxy)ethyl>-1,3,6,2-dioxazasilocane
- 2288-13-3
1-methylsilatrane
| Conditions | Yield |
|---|---|
| With potassium hydroxide In 1,4-dioxane at 80℃; for 1h; | 78% |
- 75-79-6
Methyltrichlorosilane
- 20836-42-4
2,2',2''-tris(trimethylsiloxy)triethylamine
A
- 75-77-4
chloro-trimethyl-silane
B
- 2288-13-3
1-methylsilatrane
| Conditions | Yield |
|---|---|
| at 140 - 150℃; Yields of byproduct given; | A n/a B 77% |
| Conditions | Yield |
|---|---|
| In diethyl ether at 135℃; for 2h; | 60% |
| Conditions | Yield |
|---|---|
| In xylene for 2h; Heating; | 59% |
| at 130℃; for 4h; | 14.4 g |
- 2031-67-6
Methyltriethoxysilan
- 283-56-7
2,8,9-trioxa-5-aza-1-borabicyclo[3.3.3]undecane
- 2288-13-3
1-methylsilatrane
| Conditions | Yield |
|---|---|
| With sodium ethanolate In N,N-dimethyl-formamide at 140℃; for 22h; | 50% |
| Conditions | Yield |
|---|---|
| In chloroform at 0 - 20℃; Inert atmosphere; | 50% |
- 1185-55-3
Methyltrimethoxysilan
- 74630-95-8
tris(2-hydroxyethyl)ammonium fluoride
- 2288-13-3
1-methylsilatrane
| Conditions | Yield |
|---|---|
| Heating; | 40% |
- Total:37 Page 1 of 1 1
What can I do for you?
Get Best Price
Chemistry
Molecular Structure of 1-Methylsilatrane (CAS NO.2288-13-3):
IUPAC: 5-Methyl-4,6,11-trioxa-1-aza-5-silabicyclo[3.3.3]undecane
Molecular Formula:C7H15NO3Si
Molecular Weight:189.28
EINECS:218-928-1
Density:1.12 g/cm3
Melting point:152oC
Flash Point:110oC
Boiling Point:174oC
SMILES:O1CCN2CCO[Si]1(OCC2)C
InChI:InChI=1/C7H15NO3Si/c1-12-9-5-2-8(3-6-10-12)4-7-11-12/h2-7H2,1H3
InChIKey:DZLQWMNVOBAZGC-UHFFFAOYAM
Index of Refraction:1.484
Molar Volume:168.3 cm3
Surface Tension:31.4 dyne/cm
Molar Refractivity:48.23 cm3
Enthalpy of Vaporization:46.46 kJ/mol
Vapour Pressure:0.0749 mmHg at 25oC
Toxicity Data With Reference
| 1. | orl-mus LD50:1800 mg/kg | PHARAT Pharmazie. 26 (1970),224. | ||
| 2. | ipr-mus LD50:840 mg/kg | PHARAT Pharmazie. 26 (1970),224. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Moderately toxic by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic vapors of NOx.
Safty informations about 1-Methylsilatrane (CAS NO.2288-13-3):
Risk Statements:22-36/37/38
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements:26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
TSCA:Yes
Specification
1-Methylsilatrane with cas registry number of 2288-13-3 is also known as Methylsilatrane ; 1-Methyl-2,8,9-trioxa-5-aza-1-silabicyclo(3.3.3)undecane ; 1-Methyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane ; 1-Methyl-2,8,9-trioxo-5-aza-1-silabicyclo(3.3.3)undecane ; 1-Methylsilatrane ; 2,8,9-Trioxa-5-aza-1-silabicyclo[3.3.3]undecane,1-methyl- ; 8,9-Trioxa-5-aza-1-silabicyclo[3.3.3]undecane,1-methyl-2 ; 9-Trioxa-5-aza-1-silabicyclo(3.3.3)undecane,1-methyl-8 . It is a compound with the appearance of white crystals or granular solid with a slight odor and it is insoluble in water. 1-Methylsilatrane is incompatible with strong oxidizing materials and probably combustible, so it should be stored in a tightly closed container when not in use and kept away from fire. 1-Methylsilatrane is used as a silane reagent in physical chemistry research.