Detail of "22919-49-9"

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Fidelity in the supramolecular assembly of triply and quadruply hydrogen-bonded complexes: Fidelity in the supramolecular assembly of triply and quadruply hydrogen-bonded complexes. Todd, Eric M.; Quinn, Jordan R.; Park, Taiho; Zimmerman, Steven C. ( Department of Chemistry, University of Illinois, Urbana, IL 61801, USA). Israel Journal of Chemistry, 45(3), 381-389 (English) 2005 Science from Israel. CODEN: ISJCAT. ISSN: 0021-2148. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Advancements in self-assembly and nanotechnol. will require multiple assembly "codes" to be executed simultaneously. At the mol. level this will require fidelity or orthogonality in mol. 22919-49-9 is just another one chemical used in this study. recognition events. To explore the limits of orthogonal assembly, assocn. consts. (Kassoc) and dimerization consts. (Kdimer) were measured with a known series of matched and mismatched recognition units in chloroform. Using the available complexation consts., fidelity, defined as [concn. of desired complexes]/[all complexes], was modeled for several component mixts. allowing general conditions for high fidelity assembly to be elucidated. .