Detail of "2325-27-1"

CAS Number:
2325-27-1
Name:
Benzenamine,N-(triphenylphosphoranylidene)-
Molecular Structure:
Formula:
C₂₄H₂₀NP
Molecular Weight:
353.4
Synonyms:
Phosphineimide, tetraphenyl- (6CI,7CI,8CI);(Phenylimino)triphenylphosphorane;N-(Triphenylphosphoranylidene)aniline;N-Phenylimino(triphenyl)phosphorane;N-Phenyltriphenylphosphinimine;NSC 110604;Triphenylphosphine phenylimide;Triphenyl(phenylimino)phosphorane;Tetraphenylphosphinimine;
EINECS:
219-039-1
Density:
1.07g/cm³
Melting Point:
130 °C
Boiling Point:
505.3 °C at 760 mmHg
Flash Point:
259.4 °C
Appearance:
yellow solid
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety:
26-37/39 Details

N-(Triphenylphosphoranylidene)aniline

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Synthesis and reactivity of rhenium(I) isocyanide complexes: Synthesis and reactivity of rhenium(I) isocyanide complexes. Crystal and molecular structures of ReBr(CO)4[C(NHPh)(NHCHMe2)] and ReBr(CO)3(PPh3)[C(NHPh)(NHCHMe2)]. Chen, Lih Chiou; Chen, Min Yuan; Chen, Jia Hwa; Wen, Yuh Sheng; Lu, Kuang Lieh (Inst. Chem., Acad. Sin., Taipei, Taiwan). 140716-26-3 and 2325-27-1 are cas registry numbers. These chemicals are also mentioned in this article. J. Organomet. Chem., 425(1-2), 99-111 (English) 1992. CODEN: JORCAI. ISSN: 0022-328X. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Section cross-reference(s): 75 The isocyanide complexes ReBr(CO)4(CNR) (1a, R = Pr; 1b, R = CHMe2; 1c, R = Ph) are synthesized by reaction of ReBr(CO)5 with phosphinimines via a deoxygenation mechanism. Complexes 1a and 1b react with an addnl. equiv. of Ph3P:NR to form the diisocyanide complexes ReBr(CO)3(CNR)2 (2a, R = Pr; 2b, R = CHMe2). The complex 1c reacts with isopropylamine and propylamine in ether to afford the amidinium (carbene) complexes ReBr(CO)4{C(NHPh)(NHR)} (4a, R = CHMe2; 4b, R = Pr). However, 1c does not react with Me3CNH2 under the same reaction conditions. The reaction of 4a with PPh3 leads to the formation of the complexes ReBr(CO)3(PPh3){C(NHPh)(NHCHMe2)} (5). Complexes 4a and 5 were crystallog. characterized. .

Synthesis of: Synthesis of .alpha.-chloroalkylcarbodiimides. Gorbatenko, V. I.; Fetyukhin, V. N.; Samarai, L. I. (Inst. Org. Khim., Kiev, USSR). Zh. Org. Khim., 12(11), 2472-3 (Russian) 1976. CODEN: ZORKAE. DOCUMENT TYPE: Journal CA Section: 25 (Noncondensed Aromatic Compounds) ClCRR1NCO(R = H, R1 = CCl3; R=CF3, R1 = Ph, C6H4OMe-4) reacted with Ph3P:NPh in C6H6 at 20.degree. to give 45-70% ClCRR1N:C:NPh.Except for chemicals metioned above, 2325-27-1 is also used. .