Detail of "2356-16-3"

Reference

New routes to diethyl 1-fluoromethylphosphonocarboxylates and diethyl 1-fluoromethylphosphonocarboxylic acid

New routes to diethyl 1-fluoromethylphosphonocarboxylates and diethyl 1-fluoromethylphosphonocarboxylic acid. Waschbusch, Rachel; Carran, John; Savignac, Philippe (Laboratoire Heteroelements et Coordination, URA CNRS 1499, DCPH, Ecole Polytechnique, Palaiseau 91128, Fr.). Tetrahedron, 53(18), 6391-6400 (English) 1997 Elsevier. CODEN: TETRAB.Several reagents such as 2356-16-3 is used here. ISSN: 0040-4020.Several substances like 2356-16-3 may be metioned in this study. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Di-Et 1-fluoromethylphosphonocarboxylic esters, bearing a variety of ester groups (alkyl, aryl), have been conveniently prepd. in a one-pot process, by reaction of chloroformates with 1-lithio-1-fluoro-1-(trimethylsily)methylphosphonate 2 derived from 1,1-dibromo-1-fluoromethylphosphonate. The overall yields generally range from 80 to 91 %. Reaction of 2 with CO2 leads to a novel efficient synthesis of di-Et 1-fluoromethylphosphonocarboxylic acid in 86% yield. ..

New routes to diethyl 1-fluoromethylphosphonocarboxylates and diethyl 1-fluoromethylphosphonocarboxylic acid

New routes to diethyl 1-fluoromethylphosphonocarboxylates and diethyl 1-fluoromethylphosphonocarboxylic acid. Waschbusch, Rachel; Carran, John; Savignac, Philippe (Laboratoire Heteroelements et Coordination, URA CNRS 1499, DCPH, Ecole Polytechnique, Palaiseau 91128, Fr.). Tetrahedron, 53(18), 6391-6400 (English) 1997 Elsevier. CODEN: TETRAB.Several reagents such as 2356-16-3 is used here. ISSN: 0040-4020.Several substances like 2356-16-3 may be metioned in this study. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Di-Et 1-fluoromethylphosphonocarboxylic esters, bearing a variety of ester groups (alkyl, aryl), have been conveniently prepd. in a one-pot process, by reaction of chloroformates with 1-lithio-1-fluoro-1-(trimethylsily)methylphosphonate 2 derived from 1,1-dibromo-1-fluoromethylphosphonate. The overall yields generally range from 80 to 91 %. Reaction of 2 with CO2 leads to a novel efficient synthesis of di-Et 1-fluoromethylphosphonocarboxylic acid in 86% yield. ..