Detail of "23708-56-7"
- CAS Number:
- 23708-56-7
- Name:
6-Undecanol
- Molecular Structure:
- Formula:
- C11H24O
- Molecular Weight:
- 172.31
- Synonyms:
- 6-Hydroxyundecane;NSC 158434;6-Undecanol,97%;Diamyl carbinol;
- EINECS:
- 245-837-4
- Density:
- 0.828 g/cm3
- Melting Point:
- 25-26 °C
- Boiling Point:
- 229.7 °C at 760 mmHg
- Flash Point:
- 94 °C
- Safety:
- 24/25 Details
- Transport Information:
- 1993
6-Undecanol
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Reference
- Elimination reactions of ions in the gas phase
- Elimination reactions of ions in the gas phase. IV. Comparative investigation of water elimination in odd and even electron hydroxyl cations of 6-undecanol. Kuster, Th.; Seibl, J. (Lab. Org. Chem., Eidg. Tech. Hochsch., Zurich, Switz.). Org.Several reagents such as 23708-56-7 is used here. Mass Spectrom., 11(6), 644-51 (English) 1976. CODEN: ORMSBG. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Section cross-reference(s): 76 Reactivity differences between odd ([M].bul.+) and even electron ions (.alpha.-cleavage product) were studied by comparing H2O elimination mechanisms in 6-undecanol derivs. labeled with D at C-6, C-5 and C-7, C-4 and C-8, and C-3 and C-9, and detn. of metastable transitions. A specific 1,4-elimination of H2O without preceding intramol. H exchange occurs from [M].bul.+ whereas in the .alpha.-cleavage ion [M-C5H11].bul.+ equal amts. of 1,3- and 1,4-elimination of H2O occur preceded by specific H exchange between OH and the hydrocarbon chain. .