Detail of > 24047-72-1
- CAS Number:
- 24047-72-1
- Name:
Bicyclo[3.1.1]heptan-3-one,2-hydroxy-2,6,6-trimethyl-, (1R,2R,5R)-
- Superlist Name:
- (1R,2R,5R)-(+)-2-Hydroxy-3-pinanone
- Formula:
- C10H16O2
- Molecular Structure:
![Molecular Structure of 24047-72-1 (Bicyclo[3.1.1]heptan-3-one,2-hydroxy-2,6,6-trimethyl-, (1R,2R,5R)-)](http://www.lookchem.com/300w/2010/0630/24047-72-1.jpg)
- Synonyms:
- 3-Pinanone,2-hydroxy-, (1R,2R,5R)-(+)- (8CI);Bicyclo[3.1.1]heptan-3-one,2-hydroxy-2,6,6-trimethyl-, [1R-(1a,2a,5a)]-;(+)-2-Hydroxy-3-pinanone;(+)-2-Hydroxypinocamphone;(+)-2a-Hydroxy-10b-pinan-3-one;(+)-2a-Hydroxy-3-pinanone;(1R,2R,5R)-2-Hydroxy-3-pinanone;(R,R,R)-2-Hydroxy-3-pinanone;2a-Hydroxy-10b-pinan-3-one;
- Molecular Weight:
- 168.23
- Density:
- 1.082 g/cm3
- Melting Point:
- 37-39 °C(lit.)
- Boiling Point:
- 244.999 °C at 760 mmHg
- Flash Point:
- 104.457 °C
- Appearance:
- White crystalline solid
- Safety:
- 22-24/25Details
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Reference
- Study of the chemical composition of hyssop (Hyssopus officinalis Linnaeus) essential oil
- Study of the chemical composition of hyssop (Hyssopus officinalis Linnaeus) essential oil. Joulain, Daniel (Lab. Synth. Totale Prod. Nat., Fac. Sci., Le Mans, Fr.Some commonly used reagents like 10300-03-5 is used in this experiment.). Riv. Ital. Essenze, Profumi, Piante Off., Aromi, Saponi, Cosmet., Aerosol, 58(9), 479-85 (French) 1976. CODEN: RIPOAM. DOCUMENT TYPE: Journal CA Section: 62 (Essential Oils and Cosmetics) Among the 52 substances isolated from H. officinaliss oil myrtenol methyl ether (I) [10300-03-5], methyl myrtenate (II) [30649-97-9], cis-pinic acid (IV) [61774-58-1], (+)-2-hydroxyisopinocamphone (III) [24047-72-1], and cis-pinonic acid (V) [61826-55-9] were identified for the 1st time in any plant. .alpha.-Pinene [80-56-8], camphene [79-92-5], .beta.-pinene [127-91-3], pinocamphone [547-60-4], and isopinocamphone [15358-88-0], the only substances to have been previously identified in the oil, constituted 69% of the mixt. Fourteen of the isolated substances were unidentified. .
- A convenient large scale synthesis of 2-hydroxy-3-pinanone
- A convenient large scale synthesis of 2-hydroxy-3-pinanone. Krishnamurthy, Venkat; Landi, John, Jr.; Roth, Gregory P. (Dep. Chem. Development, Boehringer Ingelheim Pharmaceuticals Inc., Ridgefield, CT 06877-0368, USA). Synthetic Communications, 27(5), 853-860 (English) 1997 Dekker. CODEN: SYNCAV. ISSN: 0039-7911. DOCUMENT TYPE: Journal CA Section: 30 (Terpenes and Terpenoids) A convenient large scale synthesis of 2-hydroxy-3-pinanone from readily available a-pinene has been developed. This two step method involves the diastereoselective dihydroxylation of a-pinene and subsequent oxidn. 24047-72-1 and 7785-26-4 which are cas registry numbers of substances are two of reagents here. of pinanediol to the hydroxy ketone. The key advantages of this method, which allows access to large quantities of this important chiral auxiliary, are high yield and ease of operation. .
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