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2437-95-8

Basic Information
CAS No.: 2437-95-8
Name: ALPHA-PINENE
Molecular Structure:
Molecular Structure of 2437-95-8 (ALPHA-PINENE)
Formula: C10H16
Molecular Weight: 136.237
Synonyms: 2437-95-8
EINECS: 201-291-9
Density: 0.879g/cm3
Melting Point: -55oC
Boiling Point: 157.9oC at 760 mmHg
Flash Point: 32.2oC
Solubility: insoluble
Appearance: liquid with a turpentine odour
Hazard Symbols: R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.; R51/53:; R65:;
Risk Codes:  Xi:Irritant;
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Safety: 26-36/37-61
PSA: 0.00000
LogP: 2.99870
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Chemistry

MF: C10H16
MW: 136.23
EINECS: 201-291-9
Flash Point: 90 °F
Melting Point: -55 °C 
refractive index: n20/D 1.465(lit.)
Density: 0.858 g/mL at 25 °C(lit.)
Boiling Point: 157.9 °C at 760 mmHg 
Appearance: Colorless transparent liquid
IUPAC Name: 4,7,7-Trimethylbicyclo[3.1.1]hept-3-ene
Solubility: Slightly soluble in water, soluble in alcohol, ether, chloroform and so the majority of organic solvents.
Synonyms: Dl-alpha-pinene ; Dl-a-pinene ; Cyclic dexadiene ; FEMA 2902 ; a-Pinene ; Bicyclo [3.1.1] hept-2-ene, 2,6,6-trimethyl ; Acintene a ; alfa-Pinene
Following is the molecular structure of alfa-Pinene (2437-95-8):

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LCLo inhalation 572ug/m3 (0.572mg/m3) BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS

SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Food and Cosmetics Toxicology. Vol. 16, Pg. 853, 1978.
mouse LD intraperitoneal > 500mg/kg (500mg/kg)   "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 4, Pg. 232, 1952.
rat LCLo inhalation 625ug/m3 (0.625mg/m3) BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS

SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Food and Cosmetics Toxicology. Vol. 16, Pg. 853, 1978.
rat LD50 oral 3700mg/kg (3700mg/kg) BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Food and Cosmetics Toxicology. Vol. 16, Pg. 853, 1978.

Safety Profile

Safety Information of alfa-Pinene (2437-95-8):
Hazard Codes: Xi,N
Xi: IrritantN: Dangerous for the environment
Risk Statements: 10-36/37/38-43-50
10: Flammable 
36/37/38: Irritating to eyes, respiratory system and skin 
43: May cause sensitization by skin contact 
50: Very Toxic to aquatic organisms 
Safety Statements: 26-36/37-61
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37: Wear suitable protective clothing and gloves 
61: Avoid release to the environment. Refer to special instructions safety data sheet 
RIDADR: UN 2368 3/PG 3
WGK Germany: 1
RTECS: DT7000000

Specification

 α-Pinene (CAS NO.2437-95-8) is an organic compound of the terpene class, one of two isomers of pinene. It is an alkene and it contains a reactive four-membered ring. It is found in the oils of many species of many coniferous trees, notably the pine. It is also found in the essential oil of rosemary (Rosmarinus officinalis). Both enantiomers are known in nature; 1S,5S- or (−)-α-pinene is more common in European pines, whereas the 1R,5R- or (+)-α-isomer is more common in North America. The racemic mixture is present in some oils such as eucalyptus oil.