CAS No.2455-24-5,Tetrahydrofurfuryl methacrylate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	2455-24-5
Name:	Tetrahydrofurfuryl methacrylate
Article Data:	7

Formula:	C9H14 O3
Molecular Weight:	170.208
Synonyms:	Methacrylicacid, tetrahydrofurfuryl ester (7CI,8CI); Furfuryl alcohol, tetrahydro-,methacrylate (8CI); Acryester THF; NSC 32634; SR 203; Sartomer SR 203;Tetrahydrofurfuryl methacrylate
EINECS:	219-529-5
Density:	1.044
Boiling Point:	52 °C0.4 mm Hg(lit.)
Flash Point:	91 ºC
Solubility:	18.99g/L at 20℃
Hazard Symbols:	R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.;
Risk Codes:	10-36/37/38
Safety:	36
Transport Information:	3272
PSA:	35.53000
LogP:	1.28470

Synthetic route

: 97-99-4
Tetrahydrofurfuryl alcohol

: 80-62-6
methacrylic acid methyl ester

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

Conditions

Conditions	Yield
With 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; di(n-butyl)tin oxide In 2-Methylpentane; cyclohexane at 85 - 100℃; for 12h; Temperature;	95%
2-methyl-propan-2-ol; lanthanum tri-tert-butylate at 25℃; for 2h;	32 %Chromat.
sodium ethanolate	15 %Chromat.
With sulfuric acid; benzene

: 97-99-4
Tetrahydrofurfuryl alcohol

: 97-63-2
methyl methacrylate

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

Conditions

Conditions	Yield
With sulfuric acid

: 97-99-4
Tetrahydrofurfuryl alcohol

: 79-41-4
poly(methacrylic acid)

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

Conditions

Conditions	Yield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃;

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 829-85-6
diphenylphosphane

: C21H25O3P

Conditions

Conditions	Yield
In 2-methyltetrahydrofuran at 90℃; for 4h; Inert atmosphere; Sealed tube; Green chemistry; regioselective reaction;	79%

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 66-99-9
β-naphthaldehyde

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-2-methyl-4-(naphthalen-2-yl)-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	75%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 123-11-5
4-methoxy-benzaldehyde

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-4-(4-methoxyphenyl)-2-methyl-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	74%

...Expand

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 34535-98-3
D,L-cis-phenylcyclopropylamine

: (tetrahydrofuran-2-yl)methyl-1-methyl-2-(phenylamino)cyclopentanecarboxylate

: (tetrahydrofuran-2-yl)methyl-1-methyl-2-(phenylamino)cyclopentanecarboxylate

Conditions

Conditions	Yield
With C60H100N4O12Rh2 In hexane at 20℃; for 18h; Schlenk technique; Inert atmosphere;	A 11% B 74%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 591-31-1
3-methoxy-benzaldehyde

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-4-(3-methoxyphenyl)-2-methyl-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	73%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 100-52-7
benzaldehyde

: 1415690-09-3
(tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-2-methyl-4-oxo-4-phenylbutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	70%
With iron(II) chloride In decane; acetonitrile at 85℃; for 1h; Inert atmosphere;	61%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 459-57-4
4-fluorobenzaldehyde

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-4-(4-fluorophenyl)-2-methyl-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	67%

...Expand

Raw Materials

97-63-2

97-99-4

80-62-6

Total:60 Page 1 of 2 1 2 Next>>

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Chemistry

Molecular Structure of Tetrahydrofurfuryl methacrylate (CAS No.2455-24-5):

Molecular Formula: C₉H₁₄O₃
Molecular Weight:
CAS No: 2455-24-5
H bond acceptors: 3
H bond donors: 0
Freely Rotating Bonds: 4
Polar Surface Area: 35.53 Å²
Index of Refraction: 1.452
Molar Refractivity: 44.62 cm³
Molar Volume: 165.2 cm³
Surface Tension: 33.7 dyne/cm
Density: 1.03 g/cm³
Flash Point: 105.6 °C
Enthalpy of Vaporization: 50.29 kJ/mol
Boiling Point: 265 °C at 760 mmHg
Vapour Pressure: 0.0094 mmHg at 25°C
IUPAC Name: Oxolan-2-ylmethyl 2-methylprop-2-enoate
InChI: InChI=1/C₉H₁₄O₃/c1-7(2)9(10)12-6-8-4-3-5-11-8/h8H,1,3-6H2,2H3
InChIKey: LCXXNKZQVOXMEH-UHFFFAOYAZ
Std. InChI: InChI=1S/C₉H₁₄O₃/c1-7(2)9(10)12-6-8-4-3-5-11-8/h8H,1,3-6H2,2H3
Std. InChIKey: LCXXNKZQVOXMEH-UHFFFAOYSA-N
Product Categories: FuransMonomers;Acrylic Monomers;Building Blocks;Heterocyclic Building Blocks;Methacrylate

Safety Profile

Risk Statements: 10-36/37/38
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 36
S36:Wear suitable protective clothing.
RIDADR: 3272
WGK Germany: 1
HazardClass: 3
PackingGroup: III
Hazardous Substances Data: 2455-24-5

Specification

Tetrahydrofurfuryl methacrylate (CAS No.2455-24-5), its synonyms are 2-Propenoic acid, 2-methyl-, (tetrahydro-2-furanyl)methyl ester ; Methacrylic acid, tetrahydrofurfuryl ester (8CI) ; Tetrahydro-2-furanylmethyl methacrylate ; Tetrahydrofuran-2-ylmethyl 2-methylprop-2-enoate ; Tetrahydrofuran-2-ylmethyl methacrylate ; 2-Methyl-acrylic acid tetrahydro-furan-2-ylmethyl ester .